安徽省菜地土壤中 3 种磺胺类抗生素的残留调查.PDF

安徽农业大学学报, 2014, 41(3): 474-478 Journal of Anhui Agricultural University [DOI] 10.13610/ki.1672-352x030 网络出版时间：2014-4-23 15:07:54 [URL]/kcms/doi/10.13610/ki.1672-352x030.html 安徽省菜地土壤中 3 种磺胺类抗生素的残留调查 陈海燕，樊 霆，叶文玲，鲁洪娟，花日茂* (安徽农业大学资源与环境学院，合肥 230036) 摘 要：采集安徽省 9 个县市共76 份菜地土壤样品，利用高效液相色谱-荧光检测器分析样品中磺胺嘧啶(SDZ)、 磺胺二甲嘧啶(SM2)和磺胺甲恶唑(SMZ)等 3 种磺胺类抗生素(SAs)的残留情况。结果表明，SDZ、SM2 和 SMZ 的 检出率分别为 6.58%、67.11%和 51.32% ，平均含量分别为0.26 、5.41 和 2.58 μg·kg-1 ，其中磺胺二甲嘧啶的检出率 和平均含量均为最高。近期施有机肥的土壤中 3 种 SAs 的总含量明显高于近期未施肥的土壤。9 个地区间菜地土壤 的磺胺嘧啶的平均含量无显著差异，但磺胺二甲嘧啶和磺胺甲恶唑的平均含量在不同地区菜地土壤中存在显著差 异。3 种 SAs 总平均含量以六安地区最高，蒙城地区最低。菜地中施用的有机肥质量需得到重视。 关键词：菜地；土壤；磺胺类抗生素 中图分类号：X53 文献标识码：A 文章编号：1672−352X (2014)03−0474−05 Investigation of three sulfonamides in soils from vegetable lands of Anhui Province CHEN Haiyan, FAN Ting,YE Wenlin, LU Hongjuan, HUA Rimao (School of Resources and Environment, Anhui Agricultural University, Hefei 230036) Abstract: Seventy-six soil samples were collected from different vegetable lands in Anhui province ，and the residues of three sulfonamides including sulfadiazine(SDZ), sulfamethazine(SM2) and sulfamethoxaz(SMZ) in the soils were determined by HPLC with fluorimetric detector. The results revealed that detectable percentages of SDZ, SM2 and SMZ were 6.58%, 67.11% and 51.32%, respectively, and the average concentrations were 0.26, 5.41 and 2.58 μg/kg for the SDZ, SM2 and SMZ, correspondingly. Both detectable percentage and average con- centration of SM2 are highest. The total concentration of three SAs was higher in the soils applied with manure than in the soils not applied with manure recently. Average concentration of SDZ had not significant difference in all samples, but SM2 and SMZ were on the contrary. The highest average SAs concentration of soil sa