玻纤网格布用有机硅改性聚丙烯酸酯乳液的制备与表征.pdfVIP

全国中文核心期刊 新 建巍粉 玻纤网格布用有机硅改性聚丙烯酸酯 乳液硇制备与表征 付强，范雪荣，王强 (江南大学纺织服装学院 教育部生态纺织重点实验室，江苏 无锡 214122) 摘要：用于混凝土工程的玻纤网格布，需要具有柔软、定位好、强度高及耐碱腐蚀等优点，现有的玻纤网格布用聚丙烯酸酯乳 液涂层存在着“热黏冷脆”、强度及耐碱性不高的缺点。通过核壳乳液聚合的方法，在壳层聚合中引入有机硅，制备一种改性聚丙烯酸 酯乳液。制得的乳液涂层具有较好的柔软性、不黏连、强度高、耐碱强度保留率可达84．2％。利用红外光谱(FT—IR)对共聚物进行表 征，表明有机硅与丙烯酸酯发生了共聚：共聚物胶膜DSC测试结果表明，有机硅用量较大时聚合物的强较理论值有所偏高 利用透 射电子显微镜(TEM)观察改性聚丙烯酸酯胶膜，确认成功制各出了具有典型核壳结构的硅改性聚丙烯酸酯乳液。 关键词：核壳聚合：玻纤网格布 有机硅；聚丙烯酸酯：耐碱强度保留率 中图分类号：TQ331．4 文献标识码：A 文章编号：1001—702X(2008)06—0044—04 Synthesis and characterization of alkoxy silane modified polyacrylate emulsion for fiberglass mesh fabric FU Qiang，FAN Xuerong，WANG Qiang (Key Laboratory of Science and Technology of Eco—Textile of Ministry of Education，School of Textiles＆ Clothing Southern Yangtze University，Wuxi 214122，Jiangsu，China) Abstract：Fiberglass mesh fabric as reinforced nmterial in concrete should have properties such as softness，good positioning， high strength and good alkali—resistivity．The conventional emulsion coating for fiberglass mesh fabric is tacky in hot circumstance and brittle in cold circumstance．It is also poor in strength and alkali—resistivity．A modified polyacrylate emulsion was prepared by core—shell polymerization and introducing an alkoxy silane to copolymerize with shell polymer．The emulsion coating showed good softness，high blocking resistance and high strength，and the retention rate of alkali—resistivity up to 84．2％．The copolymer was characterized by means of FT—IR spectrum which showed that alkoxy silane and acrylate were polymerized；the results of DSC tests showed that the Tg of polymer was slightly higher than theoretical value when the amount of alkoxy silane was high