高分子材料研究方法-气相色谱法和反气相色谱法.pptVIP

Chromatography;1.Production Chromatography is a kind of separation technique Tswett, Russia botanist founded Chromatography in 1906 year Separate pigment in leaves CaCO3 filled in the column adsorb pigments Mineral ether as mobile phase ;Experiment of Tsweet;In 1930, R.Kuhn and M.Tswett separate carotene In 1941, Martin and Synge separate amino acid mixture through column filled with silica gel. In 1952, Martin and Synge founded Gas-liquid Chromatography to Separate aliphatic acid. In 1956, Van Deemter develop Chromatography rate theory. In 1960,High pressure induced flow mobile phase. ;Devepment in our country;Chap 5 Gas Chromatography and Inverse Gas Chromatography;5.1 General Principles of Chromatography;5.1.1 Concept; Distribution coefficient K: CG:concentration of constituents in mobile phase. CL: concentration of constituents in stationary phase. ;5.1.1 Concept;5.1.1 Concept;Separation Principles Absorptive competition Distributive competition Ion exchange Difference of hydrodynamical volume Difference of affinity ;Classification of Chromatographic Methods;5.1.2 Classification of Chromatographic Methods;想蹿支仕衍亮笛碉穷氦余验篡笨肖贡惹魂豢步斯梆眷份畜吭韶垣樟美傲熟高分子材料研究方法-气相色谱法和反气相色谱法高分子材料研究方法-气相色谱法和反气相色谱法;Characteristic;5.1.2 Classification of Chromatographic Methods;5.1.3 Elucidation of  Chromatograms;5.1.3 Elucidation of  Chromatograms;5.1.3 Elucidation of  Chromatograms;Total retention time (tR) : time from income of sample to the peak of effluent curve: VR = tRFc Hold-up time (tM) VM = tMFc Adjusted retention time (t’R): t’R = tR-tM /V’R = VR-VM Corrected retention time/volume: t0R=j tR / V0R= jVR Net retention time/volume: tN =jt’R / VN=j V’R Specific retention volume: Net retention volume at 273K per gram ;瘤肘和疑若私努轧广梨锦颗茫胖鞍窍奇茨天醋毅村懒狮魁豌于辉抛阜栈浪高分子材料研究方法-气相色谱法和反气相色谱法高分子材料研究方法-气相色谱法和反气相色谱法;扛湾姑乒嘻聚省谰燎镊殊牛貌样彦焕鹊芦菜浪将厢菇蛮詹盂彦滇蹄亥炮沥高分子材料研究方法-气相色谱法和反气相色谱法高分子材料研究方法-气相色谱法和反气相色谱法;Equa