六偏磷酸钠对方解石的抑制机理-中国有色金属学报.PDF

21 2 2011 2 Vol.21 No.2 The Chinese Journal of Nonferrous Metals Feb. 2011 1004-0609(2011)02-0436-06 ( 410083) Ca2+ TD91 A Inhibition mechanism of sodium hexametaphosphate on calcite FENG Qi-ming, ZHOU Qing-bo, ZHANG Guo-fan, LU Yi-ping, YANG Shao-yan (School of Mineral Processing and Bioengineering, Central South University, Changsha 410083, China) Abstract: The effect of sodium hexametaphosphate on the flotation of calcite and its surface properties was investigated by flotation test, IR spectroscopy, adsorptive capacity and ζ potential. The flotation result shows that the inhibition of calcite is remarkable when the sodium hexametaphosphate is used. The mechanism tests indicate that hexametaphosphate is not adsorbed too much on the surface of calcite, and the active points of adsorption on the calcite are decreased for Ca2+ on the surface of calcite taken from solid phase to liquid phase under the action of hexametaphosphate, thus calcite is inhibited. Key words: calcite; sodium hexametaphosphate; flotation; inhibition mechanism [1] [5] CF [2] [3] pH [6] [4] (2007CB613602) 2010-02-01 2010-06