薄水铝石固相反应法制备Na-β-Al2O3固体电解质 Synthesis of Na-β-Al2O3 powders by solid-state reaction from boehmite.pdfVIP

薄水铝石固相反应法制备Na—F-AI。O。固体电解质 魏晓玲．顿莹莹．帅莉芳，I瑾．扬晖．沈晓丰 (南京『：业人学材料科学与l程学院．江苏幛i京210009) 摘要：以藩水铝石为原料制备AI：0，前驱粉体．随后添加Na2c0，和稳定荆MgO．并通过固相反应法来制备 Na一口__AltOs电解质。研究中通过改变前驱粉体制备时的预烧温度和保温时间．以及高温烧结制度优化烧结工艺。用 X射线衍射(XRD)目3综合热分析仪(TG—DSC)等手段对粉末的结构和热性能进行了表征：样品的电导章测试用交流阻 抗进}i刮试。结果裹明，预烧温度和保温时间对产物的纯度有显著影响。115013保温2h所得到的前驱粉料．经高温 烧结后所得到的产物中口1-AI扣棚含量最高．达到961％，300℃时样品电导犟为0013S／cm。 关键词固相反应；Na一／3“一AI扣，；固体电解质；钠一氯化镍电池 912 中囤分类号TM 文靛标识码：A 立章编号：1002 087X(2011)01—0059-04 of solid-statereactionfrom Na-口”一A1203 Synthesis powdersby boehmite WEI Jin．YANGIlui，SHEN Xiao—ling，XIEYing-ying，SHUAILi—fang，WANG Xiao—dong (Collegeo[M“erlals＆…m)dEngitJ∞ringNmJjingUniveHiltofm^∞fogyNac!jingJ“w“210009,China) Abstract：Theof solidelectrolytepowderswth wagcardedout the synthesisNa一∥一AIl01 highpurity bysintedng mixtureof and whichwasobtainedfrom boehmiteThe was Na2COjMgOprecursors calcining synthesisprocess va the re boemitecalcine timeandthe The optimizedby rying temperature，calcinehigh—temperatu sinteringprocess structure∞dthe ofthe werecharacterizedXRDandTG—DSCTheresulls crystal rmoanalysissamples by thatthe demonstrate ofthe is affectedthecalcine reandthecalcinetime pudty h口ksignificantly temperatu by f