铂络合物（platinum complex）.doc

铂络合物（platinum complex） Preparation of platinum catalyst complex I1, J., O] [L, `7, T The following are some commonly used methods for the preparation of platinum complex catalysts. Of course, there are other methods which are not discussed here. * y, Z0, I/, S1, c#, M Isopropyl alcohol solution of 1. chloro platinum acid [b] W, C9, Q6, I, m; T 3G H2ptCl*6H2O 100ml dissolved in anhydrous isopropanol, in constant temperature stirring, the soluble after standing for a long time, not only was the product, for H d- D1 / orange solution) `2 N4 | H2ptCl*6H2O + (CH3), 2CHOH, H2ptCl4 + (CH3), 2CO, +2HCl, +6H2O#, D,}, n#, V5, \5, Y9, e/, E, U During storage, the two valent platinum can be further reduced to zero valent platinum [pt (0), and Pt (0) chloroplatinic acid - isopropyl alcohol solution with strong activity, in the hydrosilylation reaction. The catalytic activity of the component is zero valent platinum and platinum two price. J$E$|8 D3 P_; M) { 2., two formic acid, two ethyl ester, coordination complex,% J, n/, I, M9, r#, H In a reflux condenser thermometer 500ml three bottle mouth, adding 1g H2ptCl*6H2O and 200ml ethanol, N2 (dry), heated to 80 DEG C reflux 2h, then cooled to 40 DEG C, evaporated ethanol, yellow viscous material, the chloroform and the solvent is removed, then the solid product (from 10 times), adding 50g phthalate two formic acid ethyl ester two dissolved solids, to filter solid slag to the adjacent benzene two formic acid ethyl ester two coordination complexes. 1 Q p- L6 e/ Z6 [3. platinum tetrahydrofuran complex: G6, n (W0, E, d+, C) In the reaction flask with a reflux condenser and a thermometer, adding 1g H2ptCl*6H2O and 200ml N2 in tetrahydrofuran, under the condition of reflux 1H, cooling Na2SO4 after drying, to filter solid slag, both the tetrahydrofuran complex solution. *]7, H#, B., k-, s:, Q, w, G1, m4., methyl siloxane, coordination complex 6 \ J4 N3 B5 Y; T, a reflux condenser, the reaction bottle thermometer, adding 32g H2ptCl*6H2O an