环保型脲醛树脂胶粘剂的低温合成方法（Method for synthesizing environment-friendly urea formaldehyde resin adhesive at low temperature）.doc

环保型脲醛树脂胶粘剂的低温合成方法（Method for synthesizing environment-friendly urea formaldehyde resin adhesive at low temperature） Urea formaldehyde resin adhesive adhesive is the main domestic and foreign wood processing industry, also known as urea formaldehyde adhesive. Urea formaldehyde resin is a low molecular weight resin produced by urea and formaldehyde in the presence of catalyst by addition and condensation reaction, when used with curing agent and additives. Besides the mixture; water resistance and durability is a little worse, has many advantages, such as easy to get raw materials, low cost, colorless or milk fat tree white, after curing, high transparency, the wood surface does not produce pollution and has the advantages of simple process, low cost. But the free formaldehyde content of UF resin in high, with the improvement of living standards, increasing awareness of environmental protection, because of formaldehyde exceed the standard of physical and mental harm caused more and more attention [i-3]. In this paper, through the control of UF ratio, using two polycondensation process of formaldehyde scavenger, with strong acidity, in the synthesis of resin, low temperature condition, which reduce the free formaldehyde content of UF resin. Also a reduction in energy consumption. The synthesis mechanism of 1 urea formaldehyde resin Urea soluble in water, easily absorb moisture caking in water, dilute acid and dilute alkali is not stable, so the urea formaldehyde resin synthesis theory can be divided into two stages, firstly, formaldehyde and urea in weak alkaline condition by addition reaction, generating a methyl pulse The performance and quality of many factors in the process of the synthesis of urea formaldehyde resin in the composition of raw materials such as molar ratio, reaction pH value, reaction temperature and reaction time will directly affect the product. Urea resin batch feeding process using the same mole ratio, improve overall performance, reduce the fre