复合使用高效减水剂及缓凝剂对水泥水化历程的影响.pdf

· 796 · 硅 酸 盐 学 报 2007 年 第35 卷第6 期 硅 酸 盐 学 报 Vol. 35 ，No. 6 2 0 0 7 年 6 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY J u n e ，2 0 0 7 复合使用高效减水剂与缓凝剂对水泥水化历程的影响 何廷树，申富强，王福川，王会安 (西安建筑科技大学材料学院，西安 710055) 摘 要：用直接测温法及X 射线衍射技术，系统研究了萘系、氨基磺酸盐系及聚羧酸盐系3 种高效减水剂，三聚磷酸钠及糖钙2 种缓凝剂及复合使 用高效减水剂与缓凝剂对水泥水化热、水化温峰、温峰出现时间及不同水化龄期Ca(OH)2 和钙矾石(ettringaite，AFt)生成量等方面的影响。结果表明： 单掺高效减水剂使水化温峰升高，温峰出现时间延迟，水化热及温峰时的Ca(OH)2 生成量增加。单掺缓凝剂使水化温峰降低，温峰出现时间大幅度延 迟，水化热及温峰时的Ca(OH)2 生成量明显减少。复合使用高效减水剂与缓凝剂时，由于协同效应，使高效减水剂的分散作用及缓凝剂的缓凝作用同 时得到加强。与单掺缓凝剂相比，复掺后水泥水化温峰出现的时间进一步延迟，水化温峰进一步降低，水化热及水化温峰时Ca(OH)2 生成量进一步减 少；但是，外加剂对AFt 生成量影响不大。 关键词：水泥水化；水化温峰；水化热；高效减水剂；缓凝剂 中图分类号：TU 文献标识码：A 文章编号：0454–5648(2007)06–0796–05 INFLUENCES OF COMBINATION OF SUPERPLASTICIZERS AND RETARDERS ON PROCESS OF CEMENT HYDRATION HE Tingshu ，SHEN Fuqiang ，WANG Fuchuan，WANG Huian (College of Materials Science and Technology, Xian University of Architecture Technology, Xian 710055, China) Abstract: By using the direct thermometry and the X-ray diffraction technique, the influences of superplasticizers, retarders and a combination of superplasticizers and retarders on cement hydration heat, the temperature peak of hydration, the time of the ap- pearance of the temperature peak, and the quantity of Ca(OH)2 and ettringite (AFt) at different ages were investigated. Three types of superplasticizers were used as followings: naphthalene-based, ammonia-based and polycarboxylicate-based superplasticizers. Two types of retarders were used as followings: sodium tripolyphosphate and calcium sugar. The results show that the three superplasticizers can raise t