磁性锂离子筛的制备及提锂性能研究李志勇1李亦然1张卫民1项.DOC

磁性锂离子筛的制备及提锂性能研究 李志勇张卫民1廉欢1陈程 （东华理工大学 水资源与环境工程学院，南昌 330013；东华理工大学 地球科学学院，南昌 330013 摘要tober法的基础上采用二氧化硅e3O4包覆钝化，界面生长、过滤烘干、煅烧后生成i1.6Mn1.6O4@SiO2@Fe3O4纳米锂离子筛抽锂后得到磁性锂离子筛。SEM表明锂锰尖晶石相对均匀包覆在钝化后的磁核粒径为nm。在配制的，1.6Mn1.6O4对锂的平衡吸附是制备的1.6Mn1.6O4@SiO2@Fe3O4对锂平衡吸附6.01 mg/g，除了Mg2+平衡吸附量达到mg/g以外，其它离子的吸附量都在1.756 mg/g以下，说明材料对Li+的吸附有较好的选择性磁性锂离子筛开展反复吸附、试验10次后，对Li+仍有良好的吸附效果，平衡吸附量稳定在5.1 mg/g磁性锂离子筛外加磁场实现与卤水分离。 锂离子筛分离TQ131.1 文献标志码：A 文章编号：1007-7545（2017）08-0000-00 Preparation of Magnetic Lithium Ion-sieve and Its Lithium Uptaking LI Zhi-yong1, LI Yi-ran1, ZHANG Wei-min1, XIANG Jun2, LIAN Huan1, CHEN Cheng3 (1. School of Water Resources and Environmental Engineering, East China University of Technology, Nanchang 330013, China; 2. Tianjin University of Science and Technology, Tianjin 300457, China; 3. School of Earth Sciences, East China University of Technology, Nanchang 330013, China) Abstract：Fe3O4 was passivated by silica based on Stober method. Lithium manganese oxide grew at silica interface. Li1.6Mn1.6O4@SiO2@Fe3O4 nanometer lithium ion-sieve precursors were produced after aging, filtration, drying, and calcining. SEM and EDX tests show that lithium manganese spinel is relatively uniformly coated on surface of passivated magnetic core. Average particle size of magnetic ion-sieve is 18.6 nm. Equilibrium adsorption capacity of lithium H1.6Mn1.6O4 is 8.78 mg/g, and adsorption capacity of H1.6Mn1.6O4@SiO2@Fe3O4 prepared for this research is 6.01 mg/g in simulated brine. In addition to Mg2+ equilibrium adsorption capacity of 5.213 mg/g, adsorption of other ions is 1.756 mg/g below, indicating that adsorption of Li+ to material has good selectivity. After repeated experiments with magnetic lithium ion sieves for 10 times, equilibrium adsorption capacity of Li+ is 5.1mg/g with desorption rate of lithium of about 95%. Magnetic lithium ion sieve has good magnetic properties with saturation magnetization of 15.14 emu/g and coercivity of 63.02 G, which can be separated from brine by magnetism separ