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B.Tech. III Semester G.G.U(B.Tech。)
B.Tech. III Semester
B.Tech. III Semester
CH2301: Chemical Engineering Thermodynamics- I ( 3 1 0 )
Unit I : Basic Concepts Definitions : Thermodynamics, approaches of thermodynamics,
System its types, Property, Equilibrium, Processes, Reversible Irreversible, Isobaric,
Isometric, Isothermal and adiabatic processes, Work, Heat, Energy.
Unit II : First Law of Thermodynamics : Law, Calculation of Internal energy, Enthalpy,
Heat capacities, work done for various processes, Application of first law to closed systems
(Isobaric, Isometric, Isothermal and Adiabatic processes) and open systems, Throttling process,
Joule – Thompson effect.
Unit III : Second Law of Thermodynamics : Heat engine and its efficiency, Heat pump,
Refrigerator, COP, Second law of Thermodynamics, Kelvin–Planck statement Clausius
Statement, Carnot’s cycle and Carnot theorems, Clausius inequality, Entropy and its
calculation, Principle of entropy increase.
Third Law of Thermodynamics : Its limitation and applications.
Unit IV : Thermochemistry :Enthalpy, Heat of reaction at constant pressure and volume,
Hess’s Law of constant heat summation , Effect of temperature on heat of reaction at constant
pressure (Kirchoff’s equation), Heat of dilution, Heat of hydrogenation, Heat of formation,
Heat of neutralization and Heat of combustion, Adiabatic flame temperature.
Unit V : Equation of State, VLE/LLE Equilibrium : Le Chatlier’s Principle, Kinetic theory,
Vapour Liquid Equilibria in Ideal solution, VLE involving high pressures and Multicomponent
systems, Consistency test for VLE data, Liquid-Liquid Equilibrium Diagrams, Equation of
state of real gas, Principles of corresponding states.
Books Recommended :
1. Chemical
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