Ni-SiO2纳米复合材料的制备及磁学性质 Preparation and Magnetic Properties of Ni-SiO2 Nanocomposites.pdfVIP

研究·分析·实验 Ni-SiO2 纳米复合材料的制备及磁学性质 1,2 1 1 1 1 1 彭 坤 ，刘富生 ，周灵平 ，李德意 ，赵慧涛 ，何 芯 （1. 湖南大学 材料学院，湖南长沙 410082 ； 2. 中南大学 粉末冶金国家重点实验室，湖南长沙 410083 ） 摘 要：以正硅酸乙酯和硝酸镍为原料，利用溶胶-凝胶法制备了纳米 NiO-SiO2 复合体，再通过氢气还原得 到 Ni-SiO2 纳米复合材料。利用 X 射线衍射（XRD ）确定了样品的相组成，利用透射电子显微镜（TEM ）观察 了样品的微观结构，利用振动样品磁强计测定了样品的磁性能。研究了成分和焙烧温度对纳米复合颗粒微观结 构和性能的影响。研究发现，所形成的纳米颗粒是以 Ni 为核心，外面包裹着非晶态 SiO2 层的核壳结构。随着 硅含量的增加，包裹层变厚，随着焙烧温度升高颗粒直径增大。讨论了制备条件和 SiO2 含量对材料的微观形貌 和磁学性能的影响。 关键词：Ni-SiO2 纳米复合材料；溶胶-凝胶法；磁性能 中图分类号：TM271 文献标识码：A 文章编号：1001-3830(2006)06-0017-03 Preparation and Magnetic Properties of Ni-SiO Nanocomposites 2 1,2 1 1 1 1 1 PENG Kun , LIU Fu-sheng , ZHOU Ling-ping , LI De-yi , ZHAO Hui-tao , HE Xin 1. College of Materials Science and Engineering, Hunan University, Changsha 410082, China; 2. State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China Abstract: Using Ni(NO ) and TEOS as nickel and silica sources, NiO-SiO nanocomposites were prepared by 3 2 2 sol-gel method. Ni-SiO nanocomposites were obtained by reducing NiO-SiO . The phase structure, microstructure and 2 2 magnetic properties of the particles was determined and measured by X-ray diffraction (XRD), transmission electron microscopy (TEM) and vibrating samples magnetometer (VSM), respectively. As the content of the silicon increases, the thickness of silica shells increases. It was found that th