钝化方式对镀锡钢板耐蚀性及铬含量的影响-材料工程.PDF

25 Effect of Chromium Content and Corrosion Resistance for T inplate with Different Passivation Methods 1, 2 1, 2 2 , , ( 1 , 11016 ) ( 2 , 110004) 1, 2 1, 2 2 SU N Jie , AN Cheng-qiang , T AN Yong ( 1 School of Environmental and Chemical Engineering, Shenyang Institute of T echnology , Shenyang 11016 , China; 2 Research Center for Corrosion and Protection of M etal, Northeast University, Shenyang 110004, China) : X , : , Cr, O Sn , Cr O , Cr( OH) Cr O , Cr( OH) , Cr 2 3 3 2 3 3 : ; ; ; XPS; : T G 174. 4 : A : 1001-43 1(2010) 03-0025-04 Abstract: T he tests, w hich consisted of chemical analysis, X-ray Photoelectron Spectroscopy ( XPS) and electrochemistry method, w ere carried out to investigate the corrosion resistance, chemical state of element chromium and the chromium content for tinplate using chemical and electrochemical pass-i vation methods. It w as show n that there existed Cr, O and Sn in the passivation film . T he total chro- mium content obtained by electrochemical method w as higher than that of the chemical method by the analysis of chemistry. T he chemical value and the composition in chromate passivation film w ere dif- ferent betw een chemical and cathode passivation. T he composition of the chemical passivation film were Cr2 O3 and Cr( OH