纸张用含氟防油剂的合成和应用研究.pdf

4 造纸化学品　2005 (2) 纸张用含氟防油剂的合成和应用研究 吴中杰 ,谢孔良 ( 东华大学 化学与化工学院 ,上海 　200051) 摘要 :合成了N羟乙基全氟辛基磺酰胺及全氟烷基磷酸酯 ,对合成条件进行了讨论 ,通过红外以及 1 19 核磁 HNMR 与 FNMR 确定了化合物的化学结构 ,并将其应用于纸张的防油整理 。将其与聚乙烯 醇与氧化淀粉一起应用于纸张的防油 ,根据国际通用测试法 Oil Kit Test - TAPPI 557 测试 ,其防油 级别可以达到 11 级 。对其防油机理也进行了探讨 。 关键词 :纸张 ;含氟防油剂 ;合成 ( ) 中图分类号 :TS727 . 3 　　文献标识码 :A 　　文章编号 :1007 - 2225 2005 02 - 0004 - 04 The Preparation and Application of Perfluoroalkylsulfonamidoalkyl Ester of Phosphorus Acid for Paper Oil Repellent WU Zhongj ie ,XIE Kongliang ( Donghua University , College of Chemistry and Chemical Engineering , S hanghai 200051, China ) Abstract : The reaction of perfluorooctanesulfonyl fluoride and ethanolamine was in the isopropyl ether . The product is N ethanol perfluorooctanesulfonamide . Nethanol perfluorooctaesulfonamide was mixed with benzene , and phosphorus oxytrichloride was added . Perfluorooctanesulfonamidoethyl phosphoryl dichloridate was obtained . The disodium salt of this product was formed by mixing equivalent amounts of the product and aqueous sodium hydroxide . The disodium salt and PVA was mixed with oxidized starch , so the sizing was obtained . When applied for the paper , using Oil Kit TestTAPPI 557 , the oil repellent grade was measured to be 11. Also the oil repellent mechanism was investigated . Key words : paper ; oilrepellent sizing ; preparation ( ) 　　纸用氟化合物防油剂对纸张进行防油整理开始 p H 25 ℃ 酸性 ,弱阳离子性 。另一类是磷酸酯型 , 于 20 世纪 50 年代 。经氟化合物防油处理的纸张对