气相色谱法程序升温测定工作场所中苯系物.doc

气相色谱法程序升温测定工作场所中苯系物[摘要] 目的 建立气相色谱法测定工作场所中苯、甲苯、乙苯、对二甲苯、间二甲苯、邻二甲苯和苯乙烯的检测方法。方法 确立本检测方法的条件试验，如色谱条件等；进行气相色谱法程序升温测定工作场所中苯系物的方法学试验。结果 7种成份在11min内完成测定并具有较好的分离效果；在（0.4～700.0）μg/L浓度范围内可获得较好的直线方程，相关系数（r）为0.9990～0.9999；最低检出限分别为：苯0.2μg/L、甲苯2.5μg/L、乙苯3.6μg/L、对二甲苯3.6μg/L、间二甲苯0.9μg/L、邻二甲苯3.4μg/L、苯乙烯1.3μg/L。精密度RSD为1.1%～3.7%，回收率为90.0%～108.1%。结论 此方法操作简便、重现性好，提高了灵敏度，适用于检测工作场所中苯系物的含量。 [关键词] 工作场所；苯系物；气相色谱 [中图分类号] R134.4[文献标识码] B [文章编号] 1673-9701（2011）21-21-02 Programmed Temperature Gas Chromatography Determination of Workplace Benzene MO Lifeng1 YE Jianbiao1 ZENG Yanling2 LU Xiufen3 1.Shenzhen Longgang District Health Inspection Institute Henggang Branch（Health Center）; 2.Shenzhen Baoan District Songgang Health Inspection Institute（Health Center）; 3.Shenzhen Longgang District Health Inspection Institute Pinghu Branch（Health Center）, Shenzhen 518115, China [Abstract] Objective To establish the detection methods of benzene, toluene, ethylbenzene, p-xylene, m-xylene, o-xylene and styrene in workplace by gas chromatography. Methods Established the conditions of this detection method, such as chromatographic conditions, and methodology of programmed temperature gas chromatography for determination of benzene in the workplace. Results 7 ingredients were measured in 11 minutes with nice separation; Good linear equation within（0.4 ~ 700.0）μg/L was obtained and correlation coefficient（r）was 0.9990-0.9999; Minimum detection limits were as follows: benzene 0.2μg/L, toluene 2.5μg/L, ethylbenzene 3.6 μg/L, p-xylene 3.6μg/L, m-xylene 0.9μg/L, o-xylene 3.4μg/L, styrene 1.3μg/L. Precision RSD was 1.1%-3.7% and average recovery was 90.0%-108.1%. Conclusion This method is simple, reproducible and can increase the sensitivity for detection of benzene content in the workplace. [Key words] Workplace；Benzene；Gas chromatography 苯系物一般是苯、甲苯、乙苯、对二甲苯、间二甲苯、邻二甲苯、苯乙烯等的统称，它是大气环境和许多污染源气体中最常见的化合物，对人体健康都具有一定的危害作用，是环境的重要污染物[1]。苯系物大多具有特殊气味，在常温常压下呈液态或固态，不溶于水。苯蒸气易燃而有一定毒性。室内的苯、二甲苯等苯系物的污染物通常由于在装修过程中以及日常