钒液流电池复合电极腐蚀的研究 study on corrosion of the assembled electrodes for the inoperative vanadium redox batteries.pdfVIP

钒液流电池复合电极腐蚀的研究 乔永莲，许 茜．张 杰，冯士超，翟玉春 (东北大学材料与冶金学院，辽宁沈阳110004) 摘要：通过扫描电镜和红外光谱等手段对失效钒电池的复合电极进行分析，研究发现正极一侧导电塑料集流板存在有 氧腐蚀。造成其中的碳流失，电阻增大；正极一侧的石墨毡也存在氧化侵蚀，石墨毡中的碳纤维坑蚀现象明显；钒电池 负极在充电过程中存在析氢过程．在石墨毡上生成一CHz--功能团。通过比较石墨毡经由浓硫酸处理和升温氧化过程的 腐蚀情况，表明钒电池充电过程中正极析出的氧原子与碳的反应活性相似于500℃以上空气中氧的反应活性。 关键词：钒电池；复合电极；石墨毡；腐蚀 911 中图分类号：TM 文献标识码：A 文章编号：1002—087 X(2008)10-0687—03 oncorrosionofthe electrodesforthe Study assembled inoperative vanadiumredoxbatteries Yu-chun QtAO Qian，ZHANGJie，FENGShi—chao，ZHAI Yong—lian，XU ofmaterialsand (School Metallurgy,NortheasternUniversi吼ShenyangLiaoning』10004,China) Abstract：Theassembledelectrodesofthe vanadiumredoxbattedeswere inoperative investigatedbyscanning electron andFouriertransforminfrared resultsshowthatthereexisted microscope(SEM) spectroscopy．The the inthe of corrosionandcarbonlosson currentcollector electrodebecause carbon-polythene positive oxygen madethe electronic felt electrode evolution，whichcomposite ofthe resistivityincreasing．Thegraphite positive from corrosion．Itwasfoundthatreaction ofatom evolvedwith felt suffered activity obviously pitting oxygen graphite wasas as intheairataround ofthe corrosion．which high oxygen’s