粉粒重排对mcfc隔膜性能的影响 effect of rearrangements for α-lialo2 particles on performance of mcfc matrix.pdfVIP

粉粒重排对MCFC隔膜性能的影响 林化新，周利，王鹏杰，李广龙，邵志刚 (中国科学院大连化学物理研究所，辽宁大连116023) 摘要：对熔融碳酸盐燃料电池(MCFC)内外隔膜最大孔径的测定。发现隔膜粉粒在外力作用下发生重排和滑移．重排 引起隔膜最大孔径等物性的变化。外力促使隔膜粉粒发生重排。产生非致密效果，但又抑制隔膜内缺陷的发展。部分外 力机械能和部分重排能转变成为粉粒的表面能．外力作用下的隔膜初期烧结模型为梯形模型。 关键词：熔融碳酸盐燃料电池：隔膜i粉粒重排和滑移；最大孔径；梯形模型 911 中图分类号：TM 文献标识码：A 文章编号：1002-087 X(2010)10-1014-05 Effectof for on of a—LiAl02 rearrangementsparticlesperformance MCFCmatrix LIN Hua-xin，ZHOULi，WANG Peng-jie，LIGuang·long，SHAOZhi·gang Institute J ofChemical ofScience,Dalian (Dalian Physics，ChineseAcademy Liaoning16023，China) underwent and themselvesinthematrix with Abstract：a—UAl02particles rearrangementsslipped impregnatedfully the under at of of2．4MPa650℃．111e modelMCFC the electrolyteassemblingpressure sintering matrix。namely be initsinitial model，could maximumdiameteralteredintoasmaller trapezium proposed sinteringprocess：the pore one the of their alteredinto eRas finallyby rearrangementsa—L．A102particlesthroughslips；themicro--poresbigger the actionofthe and mean of洳LjAl02 thediffusionof洳L|A102；the by synergistic rearrangementsparticles pore diameterWSS distributionbecame matrix wasenhancedwith enlarged；thepore-size narrowly；t