表面活性剂和胶体作业.pptVIP

Improving surfactant grafting in magnetic colloids;Magnetic nanoparticles has gained great interst due to its broad applications in various field;Magnetic nanoparticles;Coating on nanoparticles in the colloid;The strategy to obtain information;Materials;The synthesis of oleic-acid-coated magnetite nanoparticles;Defines and Method;where mOA is the mass of oleic acid adsorbed on all particles MOAw is the molecular weight of oleic acid ( MOAw=282.5) with 1.66*10-24g the atomic mass constant. ρp = 5.18 g/cm3 is the density of magnetite particle.;Finally one can obtain the grafting number from the following equation:;Fig2. a typical TEM picture of magnetite nanoparticles synthesized at the conditions R = 1.0 and Tads=85 ℃.The size-bar is 20 nm;From the FT-IR spectroscopy（not given here）we can see: The peaks around 1690 and 1718 cm-1(associated to the mean frequency of νC=O Stretching vibration of a dissociated oleic acid) were absent, indicating that all the surfactant molecules were adsorbed on the nanoparticle surface. ;Table 1 Parameters obtained from the samples through the modified coprecipitation method;Fig3. the grafting number as a function of the ratio of the molar concentration of oleic acid to the molar concentration of the iron ions (R ) for Tads =85℃;From Fig3,we can find that the adsorption of the surfactant increases with increasing the relative concentration of oleic acid.;after some mathematical manipulation one can finally arrive at the following equation for the Langmuir model;From Table 1 we can see;Fig. 4. Grafting number (ξ) as a function of the adsorption temperature for the synthesis condition of R = 0.3. Squares are experimental data and the dash line is the guide to the eyes.;The adsorption temperature was also found to have an effect on the grafting number; magnetic colloids, consisted of oleic-acid-coated magnetite nanoparticles, were synthesized by the modified co-precipitation method.