钨含量对铝合金化学镀Ni-WP 硬度和耐磨性的影响 - 中国有色金属学报.PDF

第 17 卷第 5 期 中国有色金属学报 2007 年 5 月 Vol.17 No.5 The Chinese Journal of Nonferrous Metals May 2007 文章编号：1004-0609(2007)05-0737-06 钨含量对铝合金化学镀 Ni-W-P 硬度和耐磨性的影响 胡永俊，熊 玲，蒙继龙 (华南理工大学 机械工程学院，广州 510641) 摘 要：研究铝合金化学镀 Ni-W-P 三元合金的耐磨性能，探讨钨含量对铝合金(LY12)化学镀 Ni-W-P 耐磨性和硬 度的影响。结果表明：铝合金表面化学镀 Ni-W-P 三元合金在 400 ℃加热 1 h 后，表面硬度达 HV25 1 080，表面硬 度和耐磨性均较基体提高 10 倍以上；但过高的 W 含量，使得表面硬度下降。磨损实验发现，试样产生了镀层碎 裂和剥落现象。其主要原因是由于铝合金基体与镀层热膨胀系数的差异及 Ni3P 的析出导致应力过大，引起镀层 硬度和耐磨性随着 W 含量的增加而下降。并用化学镀Ni-W-P 合金沉积机理解释了镀层成分分布特征的形成原因。 关键词：Ni-W-P 合金；化学镀；耐磨性 中图分类号：TQ 153.1 文献标识码：A Effect of content of tungsten on hardness and wear resistance of electroless Ni-W-P plating on aluminium alloy HU Yong-jun, XIONG Ling, MENG Ji-long (College of Mechanical Engineering, South China University of Technology, Guangzhou 510641, China) Abstract: The wear resistance of electroless Ni-W-P coatings on aluminium alloy was studied, the effect of content of tungsten on the wear resistance and hardness of electroless Ni-W-P deposits was discussed. The results show that the hardness of deposit heated at 400 ℃for 1 h is HV25 1 080, and the wear resistance and hardness of deposits heated at 400 ℃for 1 h are ten times more than those of aluminium matrix. With increasing content of W, the hardness of Ni-W-P coatings decreases. Disintegration and spall on the Ni-W-P deposits heated at 400 ℃ for 1 h were generated after abrasion test because of the excessive stress caused by different coefficient of thermal expansion between matrix materials and deposits and precipitat