Determination of volatile organic compounds in （测定挥发性有机化合物在）.pdfVIP

Determination of volatile organic compounds in cabin of car by an Agilent 7667A mini Thermal Desorber and an Agilent 7820A 5975E GC/MSD ENVIRONMENTAL Concern over interior air quality in cars has been rising signifi cantly in recent years, since car interiors emit hazardous volatile organic compounds (VOCs). In 2011, the Chinese government published the fi rst national standard for air quality assessment of passenger cars (GB/T 27630-2011 [1]). This standard specifi es the concentration limit of benzene, toluene, xylene, ethylbenzene, and styrene and states that VOCs testing should follow the standard method HJ/T 400-2007 [2]. This application brief presents an economical solution to measure the target compounds specifi ed in the standard, using an Agilent 7667A mini Thermal Desorber and an Agilent 7820A 5975E GC/MSD system. Experimental All of the independent chemicals including methanol, benzene, toluene, ethylbenzene, p-xylene, m-xylene, o-xylene, styrene, 1,3-dichlorobenzene,1,4-dichlorobenzene, 1,2-dichlorobenzene, n-butylacetate, and n-undecane were purchased from JK Scientifi c Ltd. Purity for each chemical was 99.5%. Methanol was used as solvent. Prepare the liquid standard solutions following the standard method GB/HJT400. For each compound, the fi nal calibration range will be from 5 ng to 1,000 ng. The optimized instrument conditions are listed in Table 1. Table 1. Optimized Instrument Conditions for TVOCs Analysis Agilent 7667A mini TD Agilent 7820A 5975E GC/MSD Tube sorbent Tenax TA Inlet temperature