奈米与微米碳化钨涂层之抗锌液腐蚀研究.pdf

奈米與微米碳化鎢塗層之抗鋅液腐蝕研究 防蝕工程　第二十四卷第一期　第33 ~ 42 頁　2010 年3 月 Journal of Chinese Corrosion Engineering, Vol. 24, No. 1, pp. 33 ~ 42 (2010) 1 1 2 黃財賞* 、黃朝寬 、曾茂仁 Corrosion of Nano-structured and Conventional Tungsten Carbide Coatings in Molten Zinc 1 1 2 Tsai-Shang Huang* , Tsao-Kuan Huang , Mao-Jen Tseng Received 20 July 2009; received in revised form 16 December 2009; accepted 16 January 2010 鈷基碳化鎢塗層目前被廣泛用於熱浸鍍鋅線之鋅槽輥的表面處理，可延長輥面使用壽 命，並提昇熱浸鍍鋅鋼板之表面品質。而近年來開發之奈米碳化鎢塗層，較傳統微米碳化 鎢塗層有較佳的材料特性。本研究利用高速火焰熔射技術製作奈米與微米碳化鎢塗層試片， 進行材料特性評估與鋅液腐蝕測試。實驗結果發現，奈米碳化鎢塗層有較高硬度、較低孔 隙率及較佳韌性，然而，其耐鋅液腐蝕卻不如微米碳化鎢塗層。鋅液腐蝕機構主要為熔融 鋅與塗層裡的鈷之交互作用，一旦鈷被擴散至鋅液中，顆粒較小的奈米碳化鎢比顆粒較大 的微米碳化鎢更容易從塗層中脫落。 關鍵詞：高速火焰熔射；鋅液腐蝕；碳化鎢；奈米塗層。 ABSTRACT WC-Co coatings are widely used for sink rolls in a continuous galvanizing line. They can extend the service life of the rolls from being attacked and improve the quality of galvanized steel sheets. Recent developed nano-structured WC-Co coatings exhibit better material properties than conventional micro-structured ones. In this study, a high velocity oxy-fuel (HVOF) spray gun was used to prepare nano-structured and conventional WC-Co coatings. Material properties and their corrosion resistances in molten zinc were evaluated. The results showed that the nano-structured WC-Co coating had a higher hardness, a lower porosity and a better toughness. However, the conventional WC-Co