水性环氧聚氨酯乳液的制备及性能研究 preparation and properties study of waterborne epoxy-polyurethane emulsion.pdfVIP

38 邓朝霞：水性环氧聚氨酯乳液的制备及性能研究 绝缘材料 2013 ，46(2) 水性环氧聚氨酯乳液的制备及性能研究 邓朝霞1,2 （1. 广东第二师范学院，广州 510303 ；2. 华南理工大学 化学与化工学院， 广州 510640） 摘要：采用聚醚二元醇(N220) 、二羟甲基丙酸（DMPA ）、甲苯二异氰酸酯（TDI-80）、1,4-丁二醇（BDO ）和环氧 树脂合成了环氧聚氨酯乳液，分析了影响该涂膜硬度和力学性能的因素。结果表明，随着R 总值、BDO 、E-20 和DMPA 的增大，环氧聚氨酯涂膜的硬度和拉伸强度增强，断裂伸长率降低；随聚醚二元醇分子量的增加，环 氧聚氨酯涂膜的拉伸强度和硬度降低，伸长率提高。当BDO 为6.4%、DMPA 为6%、E-20 为8%以及R 总取1.2~ 1.3 时，所制备的涂膜硬度最高。 关键词：环氧聚氨酯乳液；力学性能；硬度 中图分类号：TM215 ；TQ323 文献标志码：A 文章编号：1009-9239（2013 ）02-0038-05 Preparation and Properties Study of Waterborne Epoxy-polyurethane Emulsion Deng Zhaoxia1,2 (1. Department of Chemistry, Guangdong Institute of Education, Guangzhou 510303, China; 2. School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China) Abstract: An epoxy-polyurethane emulsion was synthesized by polyether diols(N220), dimethylolpropionic acid(DMPA), tolunene diisocynate(TDI-80), 1,4-butylene glycol(BDO) and epoxy resin, and the factors in- fluencing the hardness and mechanical properties of its film were discussed. The results show that with the increase of the R value, BDO, E-20 and DMPA contents, the hardness and tensile strength of the ep- oxy-polyurethane film enhance and the elongation at break decreases. With the increase of the polyether diols contents, the hardness and tensile strength of the film decrease, and the elongation at break increas- es. When the content of BDO, DMPA, E-20 is 6.4%, 6%, 8% respectively and R value is 1.2~ 1.3, the prepared film has the highest hardness. Key words: epoxy-polyurethane emulsion; mechanical prope