Sn和Ca对ZA62合金组织稳定性的影响.pdfVIP

下半月出版 Material＆Heat Treatment材料热处理技术 Sn和Ca对ZA62合金组织稳定性的影响 李淑琼，严红革，陈吉华 (湖南大学 材料科学与工程学院，湖南 长沙410082) 摘 要：采用金相显微镜、XRD、SEM和硬度测试等手段研究了Sn、Ca合金化Mg．6Zn．2AI合金在200℃长 时间退火过程中的组织演变行为和硬度变化规律。Sn合金化 ZA62合金由仅-Mg固溶体、MgZn离异共晶和 Mg2Sn析出相组成。在长时间退火过程中，含Sn的ZA62合金没有发生明显的晶粒长大，也没有析出新相。由于 MgZn相和Mg：Sn相的析出，合金硬度一时间曲线上出现两个峰值。随着退火时间的进一步延长，Mg2Sn相聚集长 大，导致合金硬度有所下降。微量Ca的加入可以加快MgZn相和Mg2Sn相的析出过程，抑制其聚集长大，使合金 硬度值在长时间退火过程中保持较高的水平，因而Mg-6Zn．2A!．3Sn．0．2Ca合金具有很高的组织稳定性。 关键词：ZA62；Sn；Ca；退火；组织稳定性 中图分类号：TGI46．2 l 文献标识码：A 文章编号：1001．3814(2008)04．0005．05 Effects of Sn and Ca Addition on Microstructural Stability Of ZA62 Magnesium Alloy LI Shuqiong，YAN Hongge，CHEN Jihua (College ofMaterials Science andEngineering,HtmanUniversity,Changsha410082，China) Abstract：Micmstmcural evolution and hardness change of the aS—caSt Mg一6Zn-2AI—baSed alloy with Sn and Ca addition during thermal exposure at 200℃ were studied by optical metallograph，X—ray diffraction，scanning electron microscopy and hardness tests．The ZA62 alloy with Sn addition is composed of e~-Mg solid solution，divorced MgZn eutectic and Mg2Sn precipitation．Neither obvious grain growth nor new phases are detected in these alloys during long-term therm al exposure．There are two peaks in the hardness VS time curves of these alloys，which corresponds to the precipitations of MgZn and Mg2Sn respectively．The overall hardness of these alloys decreaSed with time prolonging，resulting from the aggregation and coarsening of Mg2Sn．Trace addition of Ca call accelerate the initial precipitations of MgZn and Mg2Sn，and retard their coarsening and aggregation，SO that high levels of hardness is retained for a significant longer time．Therefore，Mg-6Zn-2AI-3Sn-0．2Ca alloy exhi