Y2O2S：Eu^3＋红色荧光粉的SnO2：Sb包覆研究.pdfVIP

第5卷第1期 纳米材料与应用 Vo1．5 No．1 2008年2月 NanomaterialApplication February 2008 Y202S：Eu3+红色荧光粉的SnO2：Sb包覆研究木 姜正伟， 李怀祥， 夏荣花， 于 磊 (山东师范大学化学化工与材料科学学院， 山东 济南 250014) 摘 要：采用硫融法合成了Y O S：Eu 红色荧光粉。用溶胶一凝胶法在其表面包覆了一层SnO ：Sb 透明导电薄膜。通过x射线衍射(XRD)、透射电镜(TEM)、荧光光谱(PL)和电阻测量等检测手段 分别分析了包覆处理对Y 0 S：Eu 的晶体结构、表面形貌、荧光性质以及荧光粉导电性的影响。结 果表明：通过该方法成功地在Y 0 S：Eu 表面包覆了一层连续的SnO ：Sb薄膜；当包覆量n ny2o2s=6％时，所得到的荧光粉同时具有较高的荧光强度和导电性；当掺杂量nsdn =10％，退火温度 为500℃(氧气流中退火1h)时，可以得到导电性较好的荧光粉。 关键词：Y O S：Eu ；溶胶一凝胶法；包覆；导电性 Study on Y202S：Eu Red Phosphor Coated by SnO2：Sb Film JIANG Zheng—wei， LI Huai-xiang， XIA Rong-hua， YU Lei (College of Chemistry，Chemical Engineering and Materials Science，Shandong Normal University， Jinan 250014，China) Abstract：The red phosphor Y2O2S：Eu was prepared by the flux fusion method．A layer of SnO2：Sb film was coated on the surface of the phosphor by the sol-gel method The analysis of X—Ray Diffraction(XRD)，Transmission Electron Microscope(TEM)，Photoluminescence spectrum(PL)and the measurement of the phosphors resistivty were conducted for investigating the changes of crystal structure， surface mo hology， photoluminescence properties and the resistivty between coated and uncoated phosphors respectively The results indicate that a layer of SnO2：Sb film is coated on the surface of the Y2O2S：Eu“phosphor successfully． The compatible capability of PL and conductivity are obtained when the value of ns~32／n-t2(yLs is 6％．At the same time，the influences of nsdn and temperature 011 the resistivity of the phosphors were studied． Keywor~：Y202S：Eu ；sol—gel method；coated；conductivity 中图分类号：0482．3 文献标识码：A 文章编号：1812～1918(2008)01—0006—04 0 引言