环境水中总挥发性有机硫化物的检测方法-北京玛格泰克科技发展有限.PDF

中国环境科学 2012,32(6) ：1040~1045 China Environmental Science 环境水中总挥发性有机硫化物的检测方法 * 王艳君,郑晓玲 ,何 鹰,张 栋,王保栋 ( 国家海洋局第一海洋研究所海洋生态研究中心, 山东 青岛 266061) 摘要：建立了一种捕集、解析、氧化、紫外荧光检测技术,用于水中痕量总挥发性有机硫化物的检测. 自行研制的低温捕集－热解析装置 实现水中痕量挥发性有机硫化物的富集,富集的有机硫化物在高温和助燃气作用下,充分氧化为二氧化硫,采用紫外荧光法检测二氧化硫含 量,从而间接获得水中总挥发性有机硫化物的浓度值.方法的捕集温度 5℃,解析温度 150℃,氧化温度 1000℃,气提室温度 65℃,气提时间 20min,精密度 5.5%,检测限为 6ng/L,加标回收率为 91.6%~95.1%.利用该装置对青岛市某池塘水样进行检测分析,检测结果中总挥发性有机 硫化物的含量为 1503~1911ng/L. 关键词：总挥发性有机硫化物；二氧化硫；紫外荧光；捕集；解析 中图分类号：X132 文献标识码：A 文章编号：1000-6923(2012)06-1040-06 * Research on determination of total volatile organic sulfur compounds in water. WANG Yan-jun, ZHENG Xiao-ling , HE Ying, ZHANG Dong, WANG Bao-dong (First Institute of Oceanography, State Oceanic Administration, Qingdao 266061, China). China Environmental Science, 2012,32(6) ：1040~1045 Abstract ：A detection technology was established comprising trap, desorption, oxidation and UV fluorescence determination process and used for the test of total concentration of trace volatile sulfur compounds (VSCs) in water. A cryogenic trap-thermal desorption device was developed, which was applied to capture and enrich trace volatile organic sulfur compounds. Under high temperature and combustion-supporting gas, the VSCs were completely oxidized into sulfur dioxide. Analyzing the content of sulfur dioxide through ultraviolet fluorescence method indirectly help to gain the total concentration of volatile organic sulfur compounds. The trapping temperature, gas stripping room temperature, desorption temperature, oxidation temperature were 5℃, 65℃, 150℃ and 1000 ℃ and the purge time was 20min, respectively. The det