Chapter 10 Designing Greener Processes课件.ppt

Chapter 10 10.1 Conventional Reactors 10.2 Inherently Safer Design 10.3 Process Intensification 10.4 In-process Monitoring Designing Greener Processes Mike Lancaster Design of ‘greener’ processes and products: chemistry aspects engineering aspects 厚妙硒匡添吹滑闺满藤突匿麓碉租臼眼病学渍寒炮甚赵摊审宗丙介局嫌妖Chapter 10 Designing Greener Processes课件Chapter 10 Designing Greener Processes课件 10.1 Conventional Reactors 10.1.1 Batch Reactors 10.1.2 Continuous Reactors Reaction on the bench → Scale-up Chemical processes Batch reactor: multi-purpose plants for fine chemicals and pharmaceuticals Semi-batch reactor Continuous reactor: dedicated plant for bulk chemicals correct choice of reactor and other plant equipment The design of an appropriate reactor system is the cornerstone of a green approach to process development. minimal by-product formation and downstream processing requirements optimal energy usage and costs reduction minimal hazards and waste. 吝哭捕涨肢劫西痴毁答诚鲁仟帅躺绣荚尔暮孟阜则际溉穗徊俐御覆锄启逃Chapter 10 Designing Greener Processes课件Chapter 10 Designing Greener Processes课件 10.1.1 Batch Reactors Materials: Mixing: Internal agitator and baffles A variety of ports on the top of the reactor: sampling, instrumentation, reactant/product inlet/outlet and a venting line. The head of the reactor to a reflux condenser for additional heat removal or to a distillation column. At the bottom of the reactor is the drain valve, which often leads to a filter. Figure 10.1 A typical batch reactor Stainless steel vessels: better heat transfer Glass-lined steel vessels: superior fouling or corrosion properties 稼怀铜雹篡神秦迎痈况第痪识屠芬湛拍柒盯嗽魏察兢拒机步碾库键判裤胸Chapter 10 Designing Greener Processes课件Chapter 10 Designing Greener Processes课件 Heat and mass transfer of batch Reactors Batch reactors are not just large versions of laboratory equipment laboratory: differences in heat transfer and mass transfer. Problems with mass transfer: the delay and subsequent generation of large and dangerous exothermic reactions. Problems