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Deng et al. Vol. 27, No. 8/ August 2010/J. Opt. Soc. Am. B 1659 Spectroscopic study of Cr4+-doped transparent willemite nanocrystalline glass-ceramics Degang Deng,1 Hongping Ma,2,3 Shiqing Xu,1,* Qian Wang,1 Lihui Huang,1 Shilong Zhao,1 Huanping Wang,1 and Chenxia Li1 1College of Materials Science and Engineering, China Jiliang University, Hangzhou 310018, China 2School of Mechanical and Automotive Engineering, Zhejiang University of Science and Technology, Hangzhou 310012, China 3College of Materials Science and Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China * Corresponding author: sxucjlu@ Received March 4, 2010; revised May 4, 2010; accepted May 14, 2010; posted June 23, 2010 (Doc. ID 124968); published July 27, 2010 Cr4+-doped transparent -Zn SiO glass-ceramics were prepared by heat treatment on the as-made glasses. It 2 4 was confirmed from the absorption spectra that Cr4+-doped -Zn SiO glass-ceramics are indeed a low-field 2 4 system. The broadband infrared emission centering at 1342 nm with the full width at half-maximum of more than 285 nm was observed by exciting the glass-ceramics with the excitation of an 808 nm laser diode. The observ