.紫铜在土壤浸出液中的电化学腐蚀行为研究.pdfVIP

第26 卷 第5 期 腐蚀科学与防护技术腐蚀科学与防护技术 Vol.26 No.5 2014 年9 月 CORROSION SCIENCE AND PROTECTION TECHNOLOGY Sept. 2014 紫铜在土壤浸出液中的电化学腐蚀行为研究 查方林 冯 兵 徐 松 湖南省电力公司科学研究院 长沙 410007 摘要：采用电化学阻抗谱(EIS) 和动电位扫描研究了紫铜在酸性和碱性土壤浸出液中的腐蚀行为，并用频率调 制(EFM) 方法测量了紫铜的腐蚀电流密度Icorr 。结果表明：紫铜在腐蚀过程中表面生成了钝化膜，溶液中Cl ，- NO3-和SO42-等离子会延长钝化膜的生长期；在酸性介质中，靠近溶液侧的钝化膜会转化成结构疏松的外层，膜 2 层的转化使钝化膜的保护作用减弱；腐蚀20 d 后，碱性介质中紫铜的Icorr 为4 μA/cm 左右，酸性介质中Icorr 约为 2 25 μA/cm ，紫铜耐酸蚀性较差。 关键词：紫铜，土壤浸出液 EIS EFM 钝化膜 中图分类号：TG 172.4 文献标志码：A 文章编号：1002-6495(2014)05-0446-05 Electrochemical Corrosion Behavior of Copper in Soil Extract Solution ZHA Fanglin, FENG Bing, XU Song Hunan Electric Power Corporation Research Institute, Changsha 410007, China Abstract: The electrochemical corrosion behavior of copper was studied by EIS, potentiodynamic and EFM measurements in acid and alkaline soil extract solutions. The result shows that a passive film was formed on the surface of copper during the corrosion, growth period of the passive film - - 2- could be extended due to the existence of ions like Cl ，NO3 and SO4 . In the acid soil extract so- lution, the outer portion of the passive film transformed into a loose layer, therewith its protective- ness would be lowered. After 20 d corrosion, the icorr of copper in alkaline soil extract is about 4 2 2 μA/cm , whil