高效率稀土浓缩吸附材开发 - 中国矿冶工程学会互动式网站.pdf

高效率稀土濃縮吸附材開發* Development of High Efficiency Adsorbent for Rare Earth Elements Recovery 1 2 3 4 S.C. Lo, C.F. You, Y.J. Tu, T.W. Weng By adj u sting the surface potential in the water, the inverse spinel structured nano-ferrite can adsorb rare earth 99.9% elements (REE) up to 99.9%. The technology can be applied 2015 to REE indu stry (Lo et al ., 20 15) . This study aimed at increasing the economic efficiency of saturated adsorption rate by reducing the particle size and modifying the surface property. The technology is applied to wastes containing REE in various industries to demonstrate its efficacy. Using FeSO4 prepared by hydrothermal method, the 30~90nm nano-ferrite particles, 30-90 mm, had the saturated adsorption 15mg/g rate of 15 mg/g. Using FeCl3 and FeCl2 preparation, the nano-ferrite particles, 10- 15 mm, and with further grafting 10~ 15nm functional groups, the adsorption rate increased to 24.88 24.88 mg/g mg/g. The grafting functional groups onto the nano-ferrite, NaCl 0.01 with N aCl concentration b etween 0.0 1 N~0.5N had an N~0.5 N 90% HNO3 adsorption rate higher than 90%; with HNO3 concentration 0.05 N~ 1N 96 % between 0.05N~ 1N had an desorption rate higher than 96%. The application of the said technology in the recycling test LCD Ce La of industrial REE waste showed that the recycle rate of Ce 90% 64% and La from the polishing scrap reaches 90% and 64%, Y respectively ; the recycle rate of Y from lighting industry 99% Nd (fluorescent) scrap reaches 9