Part Ⅲ Mass transfer课件.ppt

Chapter 3 Mass transfer; The purpose of studying mass transfer: 1) find concentration profile 2) get mass transfer rate;1. definition of concentration, velocity and mass flux;b). Relative velocities for mixtures;c). Relative fluxes for mixtures;2 Fick’s diffusive law (1855);3 the relation between diffusivity and t , P;The universal conservation relation: accumulate rate = income rate – output rate Transferred quantities into or out of a microelement can result from three ways: convection diffusion or conduction self generation; For mass transfer now, we take a microelement of fixed position inside fluid, i.e. Eular method. Thus, convection and diffusion and self generation exist for the microelement;Then the income rate – output rate of mass of A component by convection and diffusion is:;The accumulating mass rate can be expressed by:;Additionally, if there is no chemical reaction and ;§3.2 diffusive mass transfer;From Fick’s law:;2) diffusion with heterogeneous chemical reaction;Diffusive area;2) diffusion with heterogeneous chemical reaction;The total mass transfer rate of O2 is :;3) diffusion with homogeneous chemical reaction;Adsorbent B;4) diffusion in falling film: forced convection mass transfer;A;§3.3 Convective mass transfer 1. forced laminar flow mass transfer inside pipes;For area Ⅲ and constant mass flux ;=0;According to BCs;Find the mass transfer coefficient;;2. boundary layer theory for mass transfer;Ⅰ;2) Mass transfer equation of boundary layer Try to find a equation used to describe the concentration profile inside mass transfer boundary layer on a plate;3) Approximate integral solution of thermal equation of boundary layer;The velocity and concentration inside laminar boundary layer can be assumed as:;XL;3. Turbulent mass transfer 1) time average of mass transfer equation;Eddy mass flux;2) semi-empirical expressions of eddy mass flux;b) Prandtl mixing length try to use mixing length to express CA’ uy’;3) concentrati