聚噻吩和其衍生物_聚噻吩基复合材料的导电性能研究进展.pdf

/ 69 * , ( , 200092) 综述了聚噻吩及其衍生物的化学结构制备聚合机理导电机理导电性能和聚噻吩基复合材料的导 电性能的研 进展已有研 表明, 纯的聚噻吩及其衍生物的电导率比较低, 一般可通过掺杂来提高其电导率同 时由于聚噻吩及其衍生物具有高的Seebeck 系数以及低的热导率, 因此若将其与无机热电纳米材料复合, 将有望制 备出热电性能优良的有机/ 无机纳米复合材料 Research Progress in Electrical Properties of Polythiophene, Polythiophene Derivatives an Polythiophene Base Composites DU Yong, CAI Kefeng ( Functional Materials Research Laboratory, Tongji University, Shanghai 200092) Abstract The chemical st ruct ure, preparation, polymerizat ion mechanism an con uct ing mechanism of poly thiophene an its erivatives are int ro uce . The research progress in elect rical properties of polythiophene, polythio phene erivatives an polythiophene base composites is reviewe . These stu ies in icate that the virgin polyt hiophene an its erivatives exhibit relat ively low electrical con uctivity an that their electrical con uctivity can be increase by oping . T he virgin polythiophene an its erivatives usually have high Seebeck coefficient an very low t hermal con uctivity. Therefore, composite mat erials consisting of thermoelectric inorganic nanost ructures an polymer can inhe rit the properties of both the inorganic nanostructures an the polymer an may have synergist ic effect as well, which can result in the composites wit h goo thermoelectric properties. Key words polythiophene, mechanism, electrical con uctivity , thermoelectric properties, composites 0 [4] , , ( PTh) ,, ,