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高分子物理复习(Polymer physics review)
高分子物理复习(Polymer physics review)
Polymer physics
I. explain the following terms:
1, thermoplastic 2, configuration 3, conformation 4, glass temperature 5, cohesive energy density
6. Solvation 7, stress relaxation 8, pseudoplastic fluid 9, crosslinking structure
10, liquid crystal, liquid crystal 11, swelling (solution) 12, plasticization (toughness) 13, thermodynamic phase transition (Level 1, two)
14, Mw, Mn 15, copolymer homogeneous (heterogeneous) 16, solution parameter
Two,
Liquid crystal classification
Relationship between heat transfer velocity and T
Tg influencing factors.
Time temperature equivalence principle.
Research methods of three polymerization states.
Three,
According to the characteristics of the mechanical properties of amorphous polymers with temperature, the three mechanical states and two transition temperatures with the temperature change are explained.
Write the Avrami equation describing the crystallization of polymers and explain the meaning of the parameters. How well is the crystallization process of polymer compatible with the equation? What are the factors that affect the crystallization process of Polymers?
Explain the equilibrium melting point of polymer crystals and explain how to obtain the equilibrium melting point of polymers by experimental methods.
Three testing methods of molecular weight distribution of polymers are pointed out and their principles are briefly described.
Qualitative and quantitative information on molecular structure and morphology of polymer chains will be provided by molecular vibrational spectroscopy.
Chapter 1: geometry and structure of polymers
(1) questions and answers:
0., the content of polymer structure?
Answer: the content of polymer structure can be divided into two parts: chain structure and aggregation structure. The chain structure is divided into short-range structure and remote structure. Short-range structures include structures and configurations. The short-range structure belongs to a chemical
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