电化学阻抗谱的应用及其解析方法（Applications and analytical methods of electrochemical impedance spectroscopy）.docVIP

电化学阻抗谱的应用及其解析方法（Applications and analytical methods of electrochemical impedance spectroscopy） Documents from the network, I collected, finishing, and if there are omissions, errors, but also please correct me! Applications and analytical methods of electrochemical impedance spectroscopy A very important method in electrochemical measurement of AC impedance is an important means to study the dynamics and surface phenomena of electrode processes Especially in recent years, due to the rapid development of frequency response analyzer The test precision is more and more high impedance, ultra low frequency signal impedance spectrum also has good reproducibility, coupled with the development of computer technology, the higher the impedance spectra of the increasing degree of automation, so that we can better understand the electrode surface electric double layer structure, activation passivation film conversion, desorption process the pitting induction, development and termination and active substances 1. basic components in impedance spectra The analysis of AC impedance spectrum is usually carried out by equivalent circuit, in which the basic components include pure resistance R, pure capacitance C, impedance value 1/j, Omega C, pure inductance L, and its impedance value is j Omega L In actual measurement, a perturbation frequency of sine wave signal is applied to the Omega cell, which is the double layer as a capacitor, the resulting electrode itself, solution and electrode reaction resistance are regarded as resistance, then the equivalent circuit shown in Figure 1 Fig. 1. equivalent circuit of electrolytic cell with large area inert electrode as auxiliary electrode The AB in the figure represents the electrode of the electrolytic cell and the ends of the auxiliary electrode, respectively, Ra Rb represent the resistance of the electrode material itself, Cab said on the capacitance between the electrode and auxiliary electrode, Cd and Cdelectric double layer capacitor e