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聚醚型tpu与聚酯型tpu之间所存在的差异(The difference between TPU and polyether polyester type TPU)
聚醚型tpu与聚酯型tpu之间所存在的差异(The difference between TPU and polyether polyester type TPU)
Differences between polyether type TPU and polyester type TPU
TPU soft segments can be used in a variety of polyols, which can be broadly classified into two types: polyether series and polyester series.
Polyether type (Ether): high strength, hydrolysis resistance and high resilience, low temperature performance.
Polyester (Ester): good tensile properties, flexural properties, friction loss and solvent resistance and high temperature resistance.
Differences in soft segments affect physical properties as follows:
Tensile strength polyester series polyether series
Tear strength polyester line polyether series
Wear resistance polyester series polyether series
Drug resistance polyester polyether series
Transparent polyester series polyether series
Bacteria resistant polyester [Department] polyether series
Moisture evaporation polyester system * polyether series
Low temperature impact polyester [Department of polyether series]
1, the production of raw materials and formula difference
(1) the main raw material for the production of polyether TPU 4-4 two - diphenylmethane diisocyanate (MDI), poly tetrahydrofuran (PTMEG), 1, 4 - butanediol (BDO), the dosage of MDI is about 40%, PTMEG accounted for 40%, BDO accounted for about 20%
(2) polyester type TPU production materials are mainly 4-4 - two phenyl methane diisocyanate (MDI), 1, 4 butanediol (BDO) and adipic acid (AA), in which the amount of MDI is about 40%, AA is about 35%, and BDO is about 25%
2. Molecular weight distribution and influence
The molecular weight distribution of polyether Poisson follows the probability equation, narrow molecular weight distribution; and the relative molecular mass distribution of polyester obeys the Flory probability distribution, relative molecular mass distribution is relatively wide.
Effect of mechanical properties, molecular weight of soft segment of polyurethane polyurethane in general, assumed
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