水性聚氨酯纳米SiO2杂化材料的制备及性能研究.pdfVIP

274 精 细 化 工 V o .l 27, N o. 4 2 0 1 0 4 FINE CHEM ICALS A p r. 2 0 1 0 / SiO 2 沈一 丁, 刘 敏, 赖小娟, 王 磊 ( , 71002 1) : W PU , KH 550, SiO2 ( A 200) , - / S iO2 (W PUNS) FT IRTGD SCW PUN S , , TEM , W PU A 200 , PU A 200 w ( A 200) 0 2% , 799 nm 1399 nm, 632M Pa 204 6 M Pa, 283% 63% , TG , A 200 DSC , A 200T g : ; SiO ; KH 550; ; - ; 2 : TQ 633 : A : 1003- 5214( 2010) 04 - 03 18- 06 Preparation and Performance ofW aterborne Polyuret ane/Nanosized Silica Hybrids SH EN Y iding, L IU M in, LA I X iaojuan, WAN G Le i (K ey Laboratory of A ux iliary Chem istry Technology f or Chem ical Industry, M inistry of Educa tion, haanx i University of cience Technology, X ian 71002 1, haanx,i Ch ina) Abstract:T he po lyure hane prepo lym er w as syn hesized, and hydroph ilic nanosized silica (A 200) w as added o he prepo lym er w i h KH 550 as a coup ling agen , hen a w a erborne po lyure hane /nanosilica hybrids(W PUN S) w as ob ained by a so lge l process. T he s ruc ure and perform ance of he WPUN S film s were inves iga ed by FT IR, TG, D SC and physica l m echan ica l es ing. T he par ic le size and dis ribu ion of W PUN S hybrid em ulsion were ana ly zed by a dynam ic ligh sca er ( DLS ). The m orphology o f emu lsion w as observed by he T ransm ission E lec ron M icroscope ( TEM ) . The FT IR analysis indica es he for