某碱性铀矿石不同去钙工艺对比试验.docVIP

某碱性铀矿石不同去钙工艺对比试验 朱建伟1,2李学礼1,2孙占学1,2史维浚1,2王学刚1,2卫忠元1 (1.东华理工大学 水资源与环境工程学院，南昌 330013；2.省部共建核资源与环境教育部重点实验室，南昌 330013) 摘要：碱性铀矿石进行盐酸去钙预处理，Z1柱采用池浸换液方式去钙Z2柱采用饱水状态下连续去钙，通过调节换液频率或进液速度与盐酸酸度，使浸出液pH均保持在2左右。试验结果Z2柱累计去钙率为64.8%时，去钙周期为5.38 d，耗酸率（34%的浓盐酸质量/矿石质量）为11.49%；相比Z1柱，连续去钙周期缩短，液固比降低35%，耗酸率减少4左右。连续去钙工艺高效可行。 关键：碱性铀矿石连续去钙周期耗酸率 中图分类号：TL212.1+2 文献标志码：A 文章编号：1007-7545（2016）04-0000-00 Co Experiments on Different Calcium Carbonate Leaching Methods for Alkaline Uranium Ore ZHU Jian-wei1,2, LI Xue-li1,2, SUN Zhan-xue1,2, SHI Wei-jun1,2, WANG Xue-gang1,2, WEI Zhong-yuan1 (1. School of Water Resources and Environmental Engineering, East China Institute of Technology, Nanchang 330013, China; 2. Key Laboratory of Nuclear Resources and Environment (ECIT), Ministry of Education, Nanchang 330013, China) Abstract：Alkaline uranium ore was pretreated with hydrochloric acid to remove calcium carbonate. Tank leaching was applied in column Z1, while calcium carbonate of uranium ore was leached under condition of full water in column Z2. The results show that calcium carbonate cumulative leaching rate in column Z2 is 64.8% for only 5.38 days with acid consumption rate of 11.49%. Compared with tank leaching in column Z1, the leaching period in column Z2 is shorten by 80%, L/S drops by 35%, and acid consumption rate drops about 4 percent point. The flush leaching of calcium carbonate is efficient and feasible. Key words: alkaline uranium ore; continuous leaching of calcium carbonate; period; acid consumption rate 在我国目前已探明的铀资源储量中，碱性铀矿（CO2含量大于2%）约占30%，并且大多为硬岩铀矿，品位较低，地理位置偏远，规模小，不易开发利用[1]。因此，研究难处理、低品位碱性铀矿石的高效浸出技术具有重大意义。该类铀矿堆浸过程中浸铀周期长，浸出率较低，耗酸率很高，且在高硫酸浸出时易发生石膏板结现象[2]。针对品位较低的碱性铀矿石，在盐酸去钙后，再进行微生物浸铀[3-7]，可直接有效地解决石膏板结现象。表明CaCO3去除率达65%时，铀的浸出率可以大大提高[8]但采用池浸工艺去钙，存在去钙周期长、耗酸高等劣势。为解决此问题，本采用连续去钙工艺，以期缩短去钙周期、降低酸耗。 试验材料与方法 试验矿样取自某铀矿山碱性铀矿石，各粒径化学全分析与铀品位分析结果如表1所示。表1 各粒径化学全分析结果 Table 1 Results of chemical analysis different particle size of ore /% 粒径/mm 比例 UT CO2 CaO F Fe2O3 MgO P2O5 FeO 2.505.00 49.45 0.102 1.90 3.70