业废弃材料合成镁铝尖晶石的结构表征.pdfVIP

1 工业废弃材料合成镁铝尖晶石的结构表征 罗旭东 曲殿利 张国栋 刘海啸 （辽宁科技大学，鞍山 114051 ） 摘 要 主要研究利用工业废弃材料合成镁铝尖晶石的研究，原料采用菱镁矿风化石、用后镁碳砖细粉、合金厂铝 渣、铝型材厂铝渣，利用湿磨方式研磨，半干法成型。试样高温烧成后用 X 射线衍射设备检测试样的物相组成， 用扫描电子显微镜观察晶相的微观结构。结果发现：用铁合金厂铝渣为氧化铝源合成的镁铝尖晶石比用铝型材厂铝 渣为氧化铝源合成镁铝尖晶石特征峰明显，晶粒大小均匀，菱角分明，玻璃相含量少。随着菱镁矿风化石及用后镁 碳砖细粉加入量增加，试样中方镁石及镁橄榄石相增加；用铁合金厂铝渣与菱镁矿风化石合成的镁铝尖晶石比采用 铁合金厂铝渣与用后镁碳砖细粉合成的镁铝尖晶石晶粒尺寸大，镁铝尖晶石特征明显。 关键词 镁铝尖晶石 菱镁矿风化石 用后镁碳砖 铁合金厂铝渣 铝型材厂铝渣 Structure Characterization of Magnesia Aluminum Spinel Prepared from Industrial Waste Luo Xudong Qu Dianli Zhang Guodong Liu Haixiao （University of Science and Technology Liaoning, Anshan, 114051 ） Abstract Magnesia aluminum spinel has been perpared by using industrial waste such as decomposed magnesite, used MgO-C brick, industrial waste from ferroalloy plant and alkali corrosion slag from aluminum profile factory as the main raw materials. Wet grinding way has been used for homogenization. Specimens can be adopt semi-dry pressing. The sintered specimens are characterized by XRD and SEM to analysis the components and structure of crystalline phase. The experimental result shows that the characteristic peak of crystalline phase magnesia aluminum spinel prepared by source of alumina from industrial waste from ferroalloy plant is more obvious than that of the spinel prepared by source of alumina from alkali corrosion slag from aluminum profile factory. The spinel prepared by industrial waste from ferroalloy plant have uniform structure, more acute edges of spinel and less glass phase. The crystalline phase periclase and forsterite increase with the increasing of decomposed magnesite an