Co-Ru／γ-Al2O3催化剂的F-T合成性能.pdfVIP

油 化 工 · 34· PETR0CHEMICAL TECHN0L0GY 2008年第37卷第1期 Co—Ru／y—AI2 03催化剂的F—T合成性能 李 晨’，马向东 ，应卫勇 ，房鼎业 (1．河南丁业大学 化学化上学院，河南 郑州450001；2．华东理工大学 化工学院，上海 200237) [摘要]以NH NO3水溶液预处 的y—A1 O3为载体，采用浸渍法制备r Co／y—A1 O3催化剂，考察r添加少量贵金属Ru对Co／ y A1 0 催化剂F—T合成性能的影响。实验结果表明，添加Ru可作为氢溢流源促进co物种的还原，另外，Ru与Co相互作用形 成易还原的co Ru物种，导致催化剂表面co物种的还原温度降低，co物种容易还原，反应过程中可利用的表面金属co原子数增 加；Ru町增JJuCo／y—A12O3催化剂表lf『1桥式CO吸附的强度，使CO便于离解；添加少齄Ru能明显提高Co／y—A12O3催化剂的活性 和重质烃c；的选择性。在 料气n(H2)： (CO)=2．0、反应温度493 K、压力1．5 MPa、气态空速500 h 下，15．0％Co-O．4％ Ru／y A1，O 催化剂上CO的转化率羽1 的选择性分别为85 39％和84 28％。 [关键词]钴／y 氧化 I催化剂；钉助催化剂；F—T合成；合成气 [文章编号]1000—8144(2008)01—0034—05 [中图分类号]TQ 426．82 [文献标识码]A Catalytic Performance of Co-Ru／y-AI2 03 Catalyst for Ficher-Tropsch Synthesis Chert ，Ma Xiangdong ，Ying Weiyong ，Fang Dingye (1．School of Chemistry and Chemical Engineering，Henan University of Technology，Zhengzhou Henan 450001，China 2．School of Chemical Engineering，East China University of Science and Technology，Shanghm 200237，China) [Abstract]Co／y—A12 O3 catalyst for Ficher—Tropsch synthesis was prepared by impregnation using — Al2 O3 pretreated with NH4NO3 aqueous solution as support．Effect of adding small amount of noble metal Ru on performance of catalyst was studied．The added Ru acts as source of hydrogen spillover to promote reduction of cobalt oxides．Ru interacts with Co to form easily reducible Co—Ru species， which lowers reduction temperature of Co species on catalyst surface，and subsequently increases amount of available surface Co atoms during reaction．Ru enhances adsorptive strength of bridge—form CO，which facilitates CO to be dissociated．The addition of small amount of Ru can remarkably rise activity of catalyst and selectivity