不同pH下Ag—TiO2薄膜的光催化性能研究.pdfVIP

第37卷第1期 应 用 化 工 Vo1．37 No．1 2008年 1月 Applied Chemical Industry Jan．2008 不同pH下Ag—TiO2薄膜的光催化性能研究 周娟，郭宪英 (青岛大学化学化工与环境学院材料系，山东青岛 266071) 摘 要：以钛酸丁酯为钛源，采用溶胶一凝胶法制备Ag—TiO 溶胶，将其涂覆在载玻片上制得高光催化活性的透明薄 膜。在n[Ti(OC4H9)4]：n(C2H5OH)：n[NH(C2H4OH)2]：n(H2O)：n(AgNO3)=1：18：0．5：1：0．032的前提 下，通过改变pH值和两种不同照射光源，对甲基橙溶液进行光催化降解。结果表明，当pH值在3～6的范围，不论 哪种照射光源，甲基橙降解率可达到83％。红外光谱、能谱、热重一差热、透射电镜和原子力显微镜等测定，结果表 明，光催化薄膜由粒径1O一20 llm的AgNO，和TiO 颗粒构成，锐钛晶形结构在500—550℃转变充分。 关键词：Ag—TiO2膜；溶胶一凝胶法；光催化；pH 中图分类号：TQ 134．1 文献标识码：A 文章编号：1671—3206(2008)01—0062—05 Study on the photocatalytic activity of Ag-titanium dioxide in different pH ZHOU Juan，GUO Xian—ying (Department of Materials，College of Chemical and Environmental Engineering， Qingdao University，Qingdao 266071，China) Abstract：In this paper，the sol for Ag—TiO2 films was prepared with tetrabutyl titanate as precursor，coated on the slide glass．Under the sanle ratio of Ag／TiO2 and the same system n[Ti(OC4H9)4]：n(C2H5OH) ：n[NH(C2H4OH)2]：n(H20)：n(AgNO3)=1：18：0．5：1：0．032，investigating the effects in differ— ent pH and two lights．The photocatalytic activity of the prepared film was studied by the degradation of methyl orange；when the pH between 3～6，the conversion can up to 83％ ，whichever the two lights．The microstructure and properties of the films were studied by the ways of FTIR，EDX，DTA—TG，TEM，SEM， AFM，the results shows that：the photo—catalytic thin film is mainly composed of AgNO3 and TiO2 particles of l0～20 nm．the phase transformation of anatase was sufficiency at 500—550 oC． Key words：Ag—TiO2 film；sol—gel；photocatalysis；pH 随着人类工业文明的快速发展，环境污染问题 外光部分，而