傅立叶变换红外光谱在食用油分析上的应用.PDFVIP

第2期2011年4月 现代科学仪器 No.2 Apr. 2011 Modern Scientific Instruments 113 综述与评论 傅立叶变换红外光谱在食用油分析上的应用 1 1 2 代秀迎 　郑建明 　陈　斌 1 2 （江苏天瑞仪器分析测试中心 苏州 215300； 江苏大学 镇江 212013） 摘　要　近年来，食用植物油的问题越来越多，从地沟油到反式脂肪酸等一系列事件频繁曝光。而传统的检测方法费时 费力，本文综述了傅立叶变换红外光谱在食用油分析上的应用。该技术可以对油脂进行分类和掺杂掺假检测，同时运用光谱 数据和化学计量学方法还可以对食用油的反式不饱和脂肪酸含量、游离脂肪酸含量、碘值、皂化值及过氧化值等进行快速检测。 关键词　傅立叶红外光谱；食用油；检测；ATR 中图分类号　X785 Application of Fourier Transform Infrared Spectroscopy in the Analysis of Edible Oils 1 1 2 Dai Xiuying , Zheng Jianming ,Chen Bin (Skyray center of forcasting and analysis, Suzhou, 215300; Jiangsu University, Zhenjiang, 212013) Abstract In recent years, some incidents, which are from waste oils to trans fatty acids, were exposured frequently. There are a variety of problems about edible oils, and the traditional detecting method is diffi cult and time-consuming. The use of Fourier transform infrared spectroscopy in the study of edible oils is reviewed. This technique can characterise oils and fats and detect adulterations. At the same time, the application of spectroscopic data and chemometrics methods can rapidly determine trans- unsaturated fatty acids content, free fatty acids content, iodine value, average chain length or sa- ponifi cation number, as well as peroxide value. Key words Fourier transform infred spectroscopy; Edible Oils;Determination; ATR -1 红外光谱是波数在 14 000 ～ 50cm 的电磁波。 (Lambert - Beer) 定律为理论基础，红外光谱有许 -1 ），中红 通常将红外波谱区分为远红外（400～50cm 多可供选择的特征波长，因此，气体、液体及固体均 -1