傅里叶变换红外光谱法测定白酒中乙醇含量.PDFVIP

112 2011 39 4 , , (江苏天瑞仪器股份有限公司, 江苏 昆山 215300) : - ( ATR - FT IR), ZnSe ATR , FT IR 1 044 cm - 1 C- OH , , 0. 998 6, 0. 2% , : ; ; ; Determ ination of E thanol in A lcohol by Fourier Tran sform Infrared Spectroscopy YU L i- juan, ZH EN G J ian - m ing, ZH U W en - lei ( iangsu Skyray Instrum ent Co. , Ltd. , iangsu Kunshan 215300, Ch ina) Abs tract: The rapid determ ination of ethanol content in alcoholw as established by attenuated total reflection- Fou rier T ransform Infrared Spectroscopy(ATR- FT IR ) w ith ZnSe slot for theATR crystals and w ater for the background sam - 1 ple. W ith the peak at 1 044cm specif ied as the characteristic stretch ing v ibration of C- OH, and the area of the peak as the total absorption to elmi inate peak interference, the linear correlation coeffic ient and detection lmi it of aqueous alcohol w as 0. 998 6 and 0. 2%, respectively. This m ethod w as accurate, convenient and applicab le to the rap id determ ination of ethanol in alcohol. K ey w ord s: fourier transform infrared spectrum; attenuated total reflection; ethano;l alcohol ( FT IR ) ( 1 ) [ 1- 2] FT IR K Br N aC l, 1. 1 CaF ZnSe, , PerK inE lm er Spectrum 100; 2 FT IR , ( ATR) DTGS, ( ATR) , () ; ; ATR : 1. 2 , , , , , , 9, ( v% , ( ~ 1 m ), ) 45. 050. 055. 060. 0 65. 0 , FT ATR , IR ; , ZnSe , , ; , , , ATR - FT IR [ 3]