木质纤维类生活垃圾热解过程矿物质和碳结构的演化规律-物理.PDFVIP

第43卷 第2期 燃摇 料摇 化摇 学摇 学摇 报 Vol.43 No.2 2015年2月 Journal of Fuel Chemistry and Technology Feb. 2015 文章编号:0253鄄2409(2015)02鄄0160鄄07 木质纤维类生活垃圾热解过程矿物质和碳结构的演化规律 尹艳山,王泽忠,田摇 红,张摇 巍,何金桥,刘摇 亮,鄢晓忠 (长沙理工大学能源与动力工程学院能源高效清洁利用湖南省高校重点实验室,湖南 长沙摇 410114) 摘摇 要:使用水平管式炉,在不同热解温度(500~1000 益)条件下对废纸屑和樟树叶两种木质纤维类生活垃圾进行了热解实 验,分别采用X射线衍射(XRD)和拉曼光谱研究了样品所含矿物质和碳结构随热解温度的变化。 结果表明,废纸屑和樟树叶 含有的主要矿物分别为方解石和草酸钙,在500 益之前草酸钙全部转化为方解石,焦样中的方解石在800 益以后逐渐分解并 形成生石灰。 拉曼光谱对生活垃圾焦的碳结构变化非常敏感,低温热解时生活垃圾的大分子结构发生缩合和解聚,产生了孤 2 2 立sp 碳原子,导致峰参数D1峰半高宽和峰面积比值I / I 逐渐增大;高温热解时晶体sp 碳原子增多,导致D1峰半高宽和 D1 G I / I 逐渐减小。 焦样的碳结构有序度随热解温度升高先降低后提高。 D1 G 关键词:木质纤维;生活垃圾;热解;矿物质;碳结构;演化 中图分类号:X705摇 摇 文献标识码:A Evolution of mineral matter and carbonaceous structure during lignocellulosic municipal solid waste pyrolysis YIN Yan鄄shan,WANG Ze鄄zhong,TIAN Hong,ZHANG Wei,HE Jin鄄qiao,LIU Liang,YAN Xiao鄄zhong (School of Energy PowerEngineering,Key Laboratory of Efficient Clean Energy Utilization of Hunan Province,Changsha University of Science Technology,Changsha摇 410114,China) Abstract:Two lignocellulosic municipal solid wastes including waste paper and camphor tree leaf were pyrolyzed at temperatures of500 ~1000 益 in a horizontal tube furnace. The mineral matter and carbonaceous structure of both municipal solid wastes were characterized by X鄄ray diffraction (XRD) and Raman spectroscopy,respectively. The evolution of mineral matter and carbonaceous structure during pyrolysis was investigated. The results demonstrate that the original mineral matter in waste paper and camphor tree leaf is principally calcite and weddellite,respectively. Weddellite can completely