转底炉煤基直接还原铁矾渣回收铁锌联合工艺.docVIP

转底炉煤基直接还原铁矾渣回收铁锌联合工艺 曹晓恩，洪陆阔，齐渊洪，周和敏，郭玉华 （钢铁研究总院 先进钢铁流程及材料国家重点实验室，北京 100081） 摘要：开发了转底炉内铁矾渣含碳球团直接还原熔分回收铁烟气回收次氧化锌的联合工艺研究了工艺参数对铁矾渣中和综合回收的影响。最佳工艺条件：碱度2.5，配碳比1.4，还原温度1 300 ℃，还原时间30 min，金属化率达到98.47%，铁回收率为95%，在还原阶段锌的挥发率达到94%，熔分结束锌的挥发率接近100%。在最佳工艺参数下进行了Φ3.0 m转底炉中试试验，得到全铁含量44.50%，金属铁含量34.71%，金属化率78%的金属化球团，锌挥发率达到92%。 关键词：转底炉；铁矾渣；还原；铁锌；中试试验 中图分类号：TF813;X705 文献标志码：A 文章编号：1007-7545（2016）04-0000-00 Combined Process Iron and Zinc from Jarosite Residue by Coal-based Direct Reduction in Rotary Hearth Furnace CAO Xiao-en, HONG Lu-kuo, QI Yuan-hong, ZHOU He-min, GUO Yu-hua （State Key Laboratory of Advanced Steel Processes and Products, Central Iron and Steel Research Institute, Beijing 100081） Abstract：irect reduction-melting combined process in rotary hearth furnace (RHF) address carbon-containing pellets of jarosite residue was developed to recover iron and zinc. The effects of parameters on recovery of iron and zinc were investigated. Under the optimum conditions including basicity of R=2.5, C/O=1.4, temperature of 1 300 ℃, time of 30 min, metallization rate is 98.47%, iron recovery rate is 95%, zinc volatilizing rates is 94% at reduction stage and almost 100% in the end of melting. Pilot plant test was carried out to produce metallized pellets under the optimum conditions. Total iron content in metallized pellets is 44.50% with metallic iron of 34.71% and metallization rate of 78%, and zinc volatilizing rates is 92% in RHF (Φ=3.0 m) pilot plant test under the above mentioned optimum conditions. Key words：rotary hearth furnacejarosite residue; reduction; iron; zinc; pilot test 铁矾渣是湿法炼锌沉铁工序产生的废渣，含有丰富的铁、铅、锌、银等有价金属[1]。目前国内湿法炼锌企业堆存大量的铁矾渣，为了减少占用土地和重金属离子浸出造成的环境污染、回收有价金属提高企业经济效益，多年来进行了大量的研究[]。薛佩毅[]等提出中低温焙烧NH4Cl浸出碱浸同时回收黄钾铁矾渣中有价金属和的新工艺，最终含量达到54%左右。路殿坤[]等提出铁矾渣还原焙烧制备磁铁矿的工艺，经900 ℃还原焙烧，铁以磁铁矿形式存在，锌转化为铁酸锌，磁选精矿品位为58%，含2.5%~3%。上述工艺中，湿法工艺过程复杂，生产效率低；磁化焙烧不能有效分离铁锌，精矿中仍含有较高的，不能作为高炉冶炼的原料。 转底炉煤基直接还原工艺是处理含铁工业固废的有效手段[]，除了回收铁外能有效回收铅、锌等有价元素，具有原料适应性强、生产能力大和单位能耗相对较低的诸多优点目前国内工业应用的成功案例[]。本文采用转底炉煤基直接还原熔分工艺处理铁矾渣，