微波加热法制备电极材料活性炭 manufacture of coal based activated carbon for electrode material by microwave radiation heating.pdfVIP

第 12 期 电 子 元 件 与 材 料 Vol.25 No.12 2006 年 12 月 ELECTRONIC COMPONENTS MATERIALS D e c . 2006 研 究 与 试 制 R D 微波加热法制备电极材料活性炭 1 1 1 2 宋天秀 ，丁士华 ，李 胜 ，梁 逵 (1. 西华大学材料科学与工程学院，四川 成都 610039；2. 湖南大学材料科学与工程学院，湖南 长沙 410082) 摘要: 以煤为原料，KOH 为活化剂，采用微波辐射加热法和电阻炉加热法制备出双电层电容器用活性炭。对比研 究了两种工艺下 KOH 用量、活化时间对活性炭比电容量的影响，考察了活性炭双电层电容器的充放电特性。结果显 示：微波活化时， ζ （KOH ∶煤）为3 ∶1，起电弧时间5 min ，比电容为283.67 F/g；电阻炉活化时， ζ （KOH ∶煤） 为 4 ∶1，保温时间为 1 h，比电容为235.55 F/g 。经过 100 次循环充放电后，微波法和电阻炉法所得的活性炭的比电容 分别保持在 98.10 %和 91.04 %。 关键词: 电子技术；煤；活性炭；微波活化；电阻炉活化；电极材料；双电层电容器 中图分类号: TM53 ；TQ536.9 文献标识码:A 文章编号:1001-2028 （2006 ）12-0031-03 Manufacture of Coal Based Activated Carbon for Electrode Material by Microwave Radiation Heating 1 1 1 2 SONG Tian-xiu ，DING Shi-hua ，LI Sheng ，LIANG Kui ( 1. College of Materials Science and Engineering, Xihua University, Chengdu 610039, China; 2. College of Materials Science and Engineering, Hunan University, Changsha 410082, China) Abstract: Activated carbon for electric double layer capacitors was prepared from coal by activation with KOH through heating by microwave radiation and resistance furnace heating. Compared two methods, the influence of the proportion of KOH to coal and the time of activation were studied. Its charge-discharge performance of the coal based AC EDLC was tested. It shows that microwave