阴阳极协同处理焦化废水探究.doc

阴阳极协同处理焦化废水探究摘要：以Ti/Sb2O5+SnO2/α-PbO2/β-PbO2为阳极和C/PTFE气体扩散电极为阴极，充分利用阴阳极的协同催化作用预处理焦化废水，并考察了影响废水COD去除率的各种因素。试验结果表明，该技术能有效的降解焦化废水。在电流密度35mA/cm2、电解时间5.5h、曝气量45L/h、极板间距40mm，电解质浓度0.15mol/L、体系温度15℃、硫酸亚铁投加量2.5g/L、初始pH值为6.0-7.0的条件下，焦化废水COD去除率为43.6％，B/C值升高了58.3%，废水可生化性明显改善，为后续生化处理创造了有利条件。 关键词：阴阳极协同作用；电催化氧化；焦化废水；COD Abstract: We took Ti/Sb2O5+SnO2/α-PbO2/β-PbO2 as anode and C/PTFE as cathode to pretreat coking wastewat- er and the factors that affected COD removal rate were investigated. The results indicated that this method was well in treating coking wastewater. When the current density was 35mA/cm2, the electrolytic time was 5.5h, the rate of sparged-air was 45L/h, the electrode distance was 40mm, the electrolyte concentration was 0.15mol/L, the systemic temperature was 15℃, the dosage of FeSO4 was 2.5g/L, the initial pH was 6.0-7.0, the removal rate of COD was 43.6％, the value of B/C increased by 58.3%, the biodegradability of coking wastewater was highly improved which created good conditions for the latter biochemical process. Keywords: simultaneous effects of anode-cathode; electrocatalytic oxidation; coking wastewater; COD 中图分类号：S141.8文献标识码：A文章编号：2095-2104（2012）03-0020-02 焦化废水是原煤的高温干馏、煤气净化和化工产品精制等过程中产生的废水。该废水成分复杂，以酚类化合物为主，还含有多环芳香族和杂环类有机物等数十种性质稳定的物质，属有毒有害高浓度有机废水，处理难度很大[1-3]。传统的处理工艺难以达到令人满意的处理效果，所以研究开发经济有效的预处理技术至关重要[4,5]。 电化学氧化技术是最近发展起来的一种高级氧化处理技术，具有处理效率高、操作简便、与环境友好等优点，在水中有机污染物尤其是难生物降解或有较大毒性的污染物处理方面呈现出良好的应用前景[6-10]。本文以Ti/Sb2O5+SnO2/α-PbO2/β-PbO2为阳极，C/PTFE气体扩散电极为阴极，利用阴阳极的协同催化作用预处理焦化废水，从而降低废水的COD，提高废水的B/C值，为后续生化处理创造有利条件，并为该技术的工业应用提供理论依据和基础数据。 1 试验概况 1.1 废水水质 原水取自山东省某焦化厂未经处理的高浓度焦化废水，其废水水质见表1。 表1废水水质状况 Table 1 The quality of wastewater COD(mg/L) BOD5(mg/L) pH 6421.3-7211.5 1598.5-1750.0 6.0-7.0 1.2 试验仪器与流程 根据相关文献资料[11,12]，本试验自制了Ti/Sb2O5+SnO2/α-PbO2/β-PbO2阳极、C/PTFE气体扩散电极。此外，本试验所需仪器还有电解槽、CHI660电化学工作站、曝气装置等等。其试验流程如图1所示。 1.3 电极表征与测试 用CHI660型电化学工作站和三电极体系(参比电极：饱和甘汞电极；辅助电极：铂电极；扫描速度：50mV/S；室温)，测量制备的Ti/Sb2O5+SnO2/α-PbO2/β-PbO2阳极和