N-甲基-N＇-（2-羟基-3-乙酰氧基丙基）咪唑盐离子液体的合成.pdfVIP

化 学 工 程 师 Sum 149 NO．2 Chemical Engineer 2008年2月 ／ 文章编号：1002—1124(2008 J02—0007—03 科 研 与 N一甲基一N，一(2一羟基一3一乙酰 开 发 氧基丙基)咪唑盐离子液体的合成 刘刚，刘春萍，孙琳，温全武，李明强，薛建韬 (鲁东大学化学与材料科学学院．山东烟台264025) 摘 要：离子液体作为一种新型的绿色溶剂和催化剂已引起了化学家们的极大关注。以乙酸钠和环 氧氯丙烷为起始原料首先合成了乙酸缩水甘油酯，并优化筛选了乙酸缩水甘油酯的合成条件；再与无机酸 质子化的N一甲基咪唑反应，制备了四个N一甲基一N 一(2一羟基一3一乙酰氧基丙基)咪唑盐新型离子 液体。采用 H NMR，IR和uV对新型离子液体的结构进行了表征。测定了新型离子液体的电导率及与常 用有机溶剂之间的溶解性能。优化筛选试验结果表明，乙酸缩水甘油酯最佳的合成条件为：乙酸钠与环氧 氯丙烷的摩尔投料比为1：1 5，}_f|苯作溶剂，四丁基溴化铵为催化剂，回流反应7h。 关键词：离子液体；乙酸缩水甘油酯；合成 中图分类号：0626．2 文献标识码：A Synthesis of N—methyl—N 一(2一hydroxyi-3一acetoxyipropyi)imidazolium aS ionic liquid‘ LIU Gang，LIU Chun—ping，SUN Lin，WEN Quan—WU，LI Ming—qiang，XUE Jian—tao (School of Chemistry and Materials Science Ludong University，Yantai 264025，China) Abstract：In recent years，ionic liquid aS one kind of new green solvent and catalyst has aroused enormous interest．Four novel N—methyl—N 一(2一hydroxyl一3一acetoxylpropy1)imidazolium ionic liquid were synthe— sized by reacting epihydrin acetate with different acidic N—methylimidazolium The glycidyl ester ether was syn— thesized by sodium acetate and epichlorohydrin．Th e structures of the title compound and its intermediate were characterized by IR． H NMR and UV Solubility in commonly organic solvents and conductivity in water were de． termined．The best reaction condition to synthesize glycidyl ester was 1：1．5(mole ratio)of sodium acetate and epichlorohydrin，reacting 7h in toluene at reflux，catalyzing by tetrabutylammonium bromide． Key words：ionic liquids；glycidyl ester ether；synthesis 离子液体具有与传统有机溶剂截然不同的性