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arsenic removal from drinking water by self-made pmia nanofiltration membrane从饮用水除砷白手起家的pmia纳滤膜.pdf

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arsenic removal from drinking water by self-made pmia nanofiltration membrane从饮用水除砷白手起家的pmia纳滤膜

Advances in Chemical Engineering and Science, 2012, 2, 366-371 / 10.4236/aces.2012.23043 Published Online July 2012 (http://www.SciRP.org/journal/aces) Arsenic Removal from Drinking Water by Self-Made PMIA Nanofiltration Membrane 1* 2,3 1 1 1 Changwei Zhao , Songshan Du , Tao Wang , Jian Zhang , Zhaokun Luan 1State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing, China 2Jiangsu Association for Environmental Monitoring, Nanjing, China 3Environmental Protection Key Laboratory of Monitoring and Analysis for Organic Pollutions in Surface Water, Nanjing, China * Email: zhaocw@ Received May 22, 2012; revised June 21, 2012; accepted June 30, 2012 ABSTRACT A self-made PMIA asymmetric nanofiltration membrane was used for arsenic removal from drinking water by NF process. Effects of feed concentration, operating pressure, pH and existing ions on As(V) removal were investigated. Experimental results showed that As(V) rejection was higher than 90% in the range of investigated As feed concentra- tions. The As(V) rejection increased slightly with pressure increase, As(V) rejection was higher than 90% in the pres- sure range of 0.4 MPa to 0.8 MPa. As(V) rejection increased significantly from 83% at pH 3 to 99% at pH 9. The pres- ence of NaCl enhanced As(V) rejection in the range of feed concentration, and As(V) rejection can reach up to 99% at a feed As concentration of 100 μg/L, whereas there was a r