behaviour of ru(bpy)2+3 on the surface of water-soluble single-walled carbon nanotubes on adding other cations俄罗斯的行为(bpy)2 + 3的水溶性单壁碳纳米管表面添加其他阳离子.pdfVIP

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behaviour of ru(bpy)2+3 on the surface of water-soluble single-walled carbon nanotubes on adding other cations俄罗斯的行为(bpy)2 + 3的水溶性单壁碳纳米管表面添加其他阳离子.pdf

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behaviourofru(bpy)23onthesurfaceofwater-solublesingle-walledcarbonnanotubesonaddingothercations俄罗斯的行为(bpy)23的水溶性单壁碳纳米管表面添加其他阳离子

Journal of Surface Engineered Materials and Advanced Technology, 2012, 2, 95-99 95 /10.4236/jsemat.2012.22015 Published Online April 2012 (http://www.SciRP.org/journal/jsemat) Behaviour of Ru(bpy) 2+ on the Surface of Water-Soluble 3 Single-Walled Carbon Nanotubes on Adding Other Cations Hiroshi Shioyama National Institute of Advanced Industrial Science and Technology (AIST), Osaka, Japan. Email: shioyama.h@aist.go.jp Received January 4th, 2012; revised February 7th, 2012; accepted February 18th, 2012 ABSTRACT Behaviour of excited Ru(bpy) 2 bound to the surface of water-soluble single-walled carbon nanotubes on addition of 3 other cations have been investigated by measuring Ru(bpy) 2 luminescence. In contrast to what was observed with a 3 solution containing rod-like aggregation particles of Nafion, we found that Ru(bpy) 2 has a stronger attraction than 3 that of other cations to the sulfonic groups on the carbon nanotubes. Such a difference is attributed to the unique mi- cro-environmental characteristics of the molecular assemblies. Keywords: Nanostructures; Single-Walled Carbon Nanotube; Ru(bpy) 2 ; Luminescence Quenching 3 1. Introduction and a water-soluble single-walled carbon nanotube (SWCNT) [13]. The solubility of the SWCNT in water is The photochemical properties of tris(2,2’-bipyridine) ru-