低纯度原料制备铁基非晶合金的形成能力和磁学性能分析.pdfVIP

Trans. Nonferrous Met. Soc. China 27(2017) 857−862 Glass formation and magnetic properties of Fe-based metallic glasses fabricated by low-purity industrial materials Man ZHU, Yang FA, Zeng-yun JIAN, Li-juan YAO, Chang -qing JIN, Jun-feng XU, Rui-hua NAN, Fang-e CHANG School of Materials and Chemical Engineering, Xi’an Technological University, Xi’an 710021, China Received 1 February 2016; accepted 30 August 2016 Abstract: Fe-based metallic glasses of (Fe Nb B ) Cr (x=1, 3, 5) with high glass forming ability (GFA) and good magnetic 74 6 20 100−x x properties were prepared using low-purity raw materials. Increasing Cr content does not significantly change glass transition temperature and onset crystallization temperature, while it enhances liquidus temperature. The addition of Cr improves the GFA of the (Fe Nb B ) Cr glassy alloys compared to that in Cr-free Fe−Nb−B alloys, in which the supercooled liquid region (T ), T 74 6 20 100−x x x rg and γ are found to be 50−54 K, 0.526−0.538, and 0.367−0.371, respectively. The (Fe Nb B ) Cr glassy alloys exhibit excellent 74 6 20 100−x x 2 soft magnetic properties with high saturation magnetization of 139−161 A ·m /kg and low coercivity of 30.24−58.9 A/m. Present Fe−Nb−B−Cr glassy alloys exhibiting high GFA as well as excellent magnetic properties and low