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defluoridation of water by a biomass tinospora cordifolia由生物质金果榄defluoridation水等.pdf

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defluoridation of water by a biomass tinospora cordifolia由生物质金果榄defluoridation水等

Journal of Environmental Protection, 2012, 3, 610-616 /10.4236/jep.2012.37074 Published Online July 2012 (http://www.SciRP.org/journal/jep) Defluoridation of Water by a Biomass: Tinospora cordifolia 1 2 2 Piyush Kant Pandey , Madhurima Pandey , Rekha Sharma 1Bhilai Institute of Technology, New Raipur, India; 2Centre for Environmental Science Engineering, Department of Engineering Chemistry, Bhilai Institute of Technology, Durg, India. Email: drpiyush_pandey@, drmadhurima_pandey@, rekha.sharma.ssitm@ Received March 11th, 2012; revised April 15th, 2012; accepted May 17th, 2012 ABSTRACT This research is focused on the search of a biomass for the sequestration of fluoride from drinking water. Defluoridation of water was studied by batch experiments in biosorption process. The biomass was found to reduce fluoride to permis- sible limit 1.5 mg/L as prescribed by WHO. The efficiency of the sorption process was investigated under different ex- perimental parameters such as pH 7, standing time 120 min and biomass doses 7.0 g with 5 mg/L concentration of fluo- ride. Neutral pH was identified as the optimum condition of the medium and 120 minutes was the best contact time for maximum fluoride adsorption. The experimental data was found good fitting to Langmuir and Freundlich isotherm models. In interference study tolerable effect was found with 50 mg/L concentration of co-ions, whereas increasing the concentration of co-ions retarded the fluoride removal capacity in some extent. FT-IR spectrum analysis showed fluo- ride binding in the different frequency ranges of the biomass. Eventually, this plant biomass is recommended as a suit- able and low cost adsorbent to reduce fluoride into standard permissible limit. Keywords: Sequestration; Defluoridation; Biosorption; FT-IR Spectrum; Permissible 1. Introduction