corrosion behavior of tin-plated carbon steel and aluminum in nacl solutions using electrochemical impedance spectroscopy废料碳钢的腐蚀行为和铝使用电化学阻抗谱在氯化钠的解决方案.pdfVIP

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corrosion behavior of tin-plated carbon steel and aluminum in nacl solutions using electrochemical impedance spectroscopy废料碳钢的腐蚀行为和铝使用电化学阻抗谱在氯化钠的解决方案.pdf

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corrosion behavior of tin-plated carbon steel and aluminum in nacl solutions using electrochemical impedance spectroscopy废料碳钢的腐蚀行为和铝使用电化学阻抗谱在氯化钠的解决方案

Journal of Minerals Materials Characterization Engineering, Vol. 7, No.4, pp 331-346, 2008 jmmce.org Printed in the USA. All rights reserved Corrosion Behavior of Tin-Plated Carbon Steel and Aluminum in NaCl Solutions Using Electrochemical Impedance Spectroscopy a b* a a B.O. Oni , N.O. Egiebor , N.J. Ekekwe , and A. Chuku aDepartment of Electrical Engineering b Environmental Engineering Program, Department of Chemical Engineering Tuskegee University, Tuskegee, AL 36088, USA * Author for Communications: E-mail: Egiebor@tuskegee.edu Phone: 334-724-4265, Fax: 334-724-4397 Abstract The corrosion behavior of both tin-plated carbon steel and aluminum (Al 1100) in NaCl solutions were studied using electrochemical impedance spectroscopy (EIS). The study objectives were to compare their corrosion behavior in concentrated brine solution, establish the equivalent electrical circuit diagrams of their corrosion phenomena, and consequently develop steady-state corrosion models for estimating the corrosion rates in the given solution. The steady-state corrosion rates for the tin-plated carbon steel increased significantly when the concentration of NaCl was increased from 1.0M to 1.5M. The increase in corrosion rate of the tin-plated steel is attributed to reduced charge transfer resistance due to the breakdown of the surface tin plating at high chloride concentrations. In contrast, there was little incremental change in the corrosion r